Affordable event and monthly rain samplers: Improving isotopic datasets to understand meteorological processes.

Rationale: Water-stable isotopes in rainfall are powerful tracers of atmospheric processes at different spatial and temporal scales. However, commercially available rain samplers for isotopic analysis are prohibitively expensive, especially for high spatial resolution networks and studies conducted in developing countries. A low-cost, simple, and robust sampler was designed for event and monthly rainfall samplings.

Identification of riverbank filtration sites at watershed scale: A geochemical and isotopic framework.

Identifying groundwater wells performing riverbank filtration (RBF) is crucial to ensure safe drinking water through vulnerability assessment plans adapted to these hybrid water sources. Nonetheless, RBF is often unintentional or insufficiently documented and official inventories are scarce. We developed a user-friendly geochemical and isotopic framework for the in-situ identification of RBF facilities.

Optimizing short time-step monitoring and management strategies using environmental tracers at flood-affected bank filtration sites.

Bank filtration is a popular pre-treatment method to produce drinking water as it benefits from the natural capacity of the sediments to attenuate contaminants. Under flood conditions, bank filtration systems are known to be vulnerable to contamination, partly because flow patterns may evolve at short timescales and result in a rapid evolution of the origin and travel times of surface water in the aquifer. However, high frequency monitoring for water quality is not common practice yet, and water quality management decisions for the operation of bank filtration systems are typically based on weekly to monthly assays.

A portrait of wellbore leakage in northeastern British Columbia, Canada.

Oil and gas well leakage is of public concern primarily due to the perceived risks of aquifer contamination and greenhouse gas (GHG) emissions. This study examined well leakage data from the British Columbia Oil and Gas Commission (BC OGC) to identify leakage pathways and initially quantify incident rates of leakage and GHG emissions from leaking wells. Three types of leakage are distinguished: "surface casing vent flow" (SCVF), "outside the surface casing leakage" (OSCL), and "cap leakage" (CL).

A New Technique to Determine the Phosphate Oxygen Isotope Composition of Freshwater Samples at Low Ambient Phosphate Concentration.

The oxygen isotope composition of dissolved inorganic phosphate (δO) offers new opportunities to understand the sources and the fate of phosphorus (P) in freshwater ecosystems. However, current analytical protocols for determining δO are unable to generate reliable data for samples in which ambient P concentrations are extremely low, precisely the systems in which δO may provide new and important insights into the biogeochemistry of P. In this Article, we report the development, testing and initial application of a new technique that enables δO analysis to be extended into such ecosystems.

Assessing the potential of cross-contamination from oil and gas hydraulic fracturing: A case study in northeastern British Columbia, Canada.

This paper presents the various tools and data sources in British Columbia (Canada) that can be used by environmental consultants to assess the potential of cross-contamination between shale gas formation fluids and shallow aquifers from hydraulic fracturing and related oil and gas activities. A systematic approach for evaluating the potential of cross-contamination using these data sources is applied to a specific case study at an undisclosed location in the northeastern part of the province. This approach includes defining and then evaluating the basic criteria for assessing the potential of cross-contamination.

Improved accuracy and precision of water stable isotope measurements using the direct vapour equilibration method.

Rationale: A method to measure the δ H and δ O composition of pore water in soil samples using direct vapour equilibration and laser spectrometry was first described in 2008, and was rapidly adopted. Here, we describe an improved setup to measure pore water δ H and δ O values through direct vapour equilibration with a laser spectrometer, combining a liquid and a vapour mode for water isotope analyses, and resulting in improved accuracy.

Methods: We first tested new gas sampling bags as part of the equilibration protocol.

Regional assessment of concentrations and sources of pharmaceutically active compounds, pesticides, nitrate, and E. coli in post-glacial aquifer environments (Canada).

There is growing concern worldwide about the exposure of groundwater resources to pharmaceutically active compounds (PhACs) and agricultural contaminants, such as pesticides, nitrate, and Escherichia coli. For regions with a low population density and an abundance of water, regional contamination assessments are not carried out systematically due to the typically low concentrations and high costs of analyses. The objectives of this study were to evaluate regional-scale contaminant distributions in untreated groundwater in a rural region of Quebec (Canada).

Impact of climate changes during the last 5 million years on groundwater in basement aquifers.

Climate change is thought to have major effects on groundwater resources. There is however a limited knowledge of the impacts of past climate changes such as warm or glacial periods on groundwater although marine or glacial fluids may have circulated in basements during these periods. Geochemical investigations of groundwater at shallow depth (80-400 m) in the Armorican basement (western France) revealed three major phases of evolution: (1) Mio-Pliocene transgressions led to marine water introduction in the whole rock porosity through density and then diffusion processes, (2) intensive and rapid recharge after the glacial maximum down to several hundred meters depths, (3) a present-day regime of groundwater circulation limited to shallow depth.