A brain tumor is an abnormal growth of cells within the brain or surrounding tissues, which can be either benign or malignant. Brain tumors develop in various regions of the brain, each affecting different functions such as movement, speech, and vision, depending on their location. Early prediction of brain tumors is crucial for improving survival rates and treatment outcomes.
View Article and Find Full Text PDFLithium-metal batteries are currently recognized as promising next-generation technologies owing to their high energy density. Solid polymer electrolytes, particularly those based on polyethylene oxide (PEO), are lauded for their leakage resistance, safety, and flexible design. Despite the ongoing fire safety- and ionic conductivity-related concerns, a novel noncombustible solid polymer electrolytes with superior ionic conductivities are introduced here with additive decabromodiphenyl ethane and zeolite.
View Article and Find Full Text PDFBackground: Limited interventions exist on reducing unwanted screen time (ST) among children from low- and middle-income countries (LMICs), so we developed and assessed the effectiveness of the program to lower unwanted media screen time (PLUMS) among children aged 2-5 years in Chandigarh, Union Territory, North India.
Methods: An open-label randomized control parallel group trial per CONSORT guidelines was conducted among randomly selected 340 families with children aged 2-5 (±3 months) years in Chandigarh, India. PLUMS was implemented at the family level with a focus on modifying the home media environment and targeted individual-level interventions using parent and child modules for 2 months.
Lithium-ion batteries (LIBs) have revolutionized portable electronics, yet their conventional graphite anodes face capacity limitations. Integrating graphene and 3D molybdenum disulfide (MoS) offers a promising solution. Ensuring a uniform distribution of 3D MoSnanostructures within a graphene matrix is crucial for optimizing battery performance and preventing issues like agglomeration and capacity degradation.
View Article and Find Full Text PDFA distinguished triplet splitting pattern for the N-H couplings in the proton signals of a series of protonated nitrogen bases-aliphatic and aromatic amines, as well as pyridines-with the weakly coordinating tetrakis(pentafluorophenyl)borate anion, [B(CF)], is observed for the first time in nonaqueous media at room temperature. The effects of ion pairing, solvent parameters, and correlation between the δ, , and p values are reported.
View Article and Find Full Text PDFMeniscus tears are among the common knee injuries in sports, with arthroscopic meniscectomy being one of the most commonly performed orthopedic procedures. Return to sports of the same level following arthroscopic meniscectomy is an important aspect for athletes. Numerous factors may influence the time required for athletes to resume sports activities after meniscectomy.
View Article and Find Full Text PDFGraphene oxide-based composite membranes have received enormous attention for highly efficient water desalination. Herein, we prepare arginine/graphene oxide (Arg/GO) composite membranes by surface functionalizing GO nanosheets with arginine amino acid. Arginine has a unique combination of hydroxyl and amino functional groups that cross-link GO nanosheets through hydrogen bonding and electrostatic interactions.
View Article and Find Full Text PDFAnterior cruciate ligament (ACL) tears are a prevalent and debilitating injury among athletes, often accompanied by concurrent meniscal and chondral injuries. This study aimed to present a comprehensive investigation into the patterns and prevalence of meniscal and chondral injuries in athletes with ACL tears. This is a cross-sectional study conducted on 600 athletic patients with ACL tears planned for reconstruction in a duration of five years.
View Article and Find Full Text PDFHydrogen heralded as a promising renewable and environmentally friendly energy carrier, carries inherent risks owing to its highly flammable nature. A mere 4 % concentration of hydrogen in the air can trigger an explosion. To counteract this peril, a composite material comprising PbO-ZnO (2 : 1) was synthesized, characterized, and subsequently employed to fabricate a hydrogen sensing device.
View Article and Find Full Text PDFVarious strategies have been adapted to fabricate stable organic-inorganic hybrid perovskite (PVT) solar cells (PSCs). The triple-cation (CHNH (MA), CH(NH) (FA), and Cs) along with dual-anion (I and Br)-based PVT (TC-PVT) layer offers better stability than single cation-based PVTs. The deprivation of the PVT absorber is also influenced by the interface of the absorber with the charge transport layer (electron transport layer (ETL) and hole transport layer (HTL)).
View Article and Find Full Text PDFIntegration of optical technologies in biomedical sciences permitted light manipulation at smaller time-length scales for specific detection and imaging of biological entities. Similarly, advances in consumer electronics and wireless telecommunications strengthened the development of affordable and portable point-of-care (POC) optical devices, circumventing the necessity of conventional clinical analyses by trained personnel. However, many of the POC optical technologies translated from bench to bedside require industrial support for their commercialization and dissemination to the population.
View Article and Find Full Text PDFHybrid hydrogels based on n-isopropylacrylamide, zwitterionic comonomer, and graphene oxide were synthesized to study their physical and mechanical properties. The compositional variation largely influenced the swelling characteristics of the hybrid hydrogels compared to mechanical properties, i.e.
View Article and Find Full Text PDFPhotoactive polymer and quantum dots (QDs)/nanocrystals (NCs)-based bulk heterojunction (BHJ) solar cells have the combined positivity of organic semiconductors and inorganic components, which can enable a high carrier mobility and absorption coefficient. Additionally, the NCs also provide the opportunity to tune the band gap to obtain enhanced absorption in a broad solar spectrum. Among the semiconductors, lead chalcogenide NCs are of particular interest due to their good photosensitivity in the near-infrared (NIR) region of the solar spectrum.
View Article and Find Full Text PDFTo combat the adverse environmental effects of fossil fuel burning for power generation and to conserve it for strategic use, new, clean, and renewable energy sources are being utilized for power generation. The study presents techno-economic analysis of a grid-connected solar photovoltaic (PV) power plant to partially meet the energy consumption of the people of Kuttiady village in Kerala, India. The proposed 2315.
View Article and Find Full Text PDFIn this work, we developed a facile and environmentally friendly synthesis strategy for large-scale preparation of Cr-doped hybrid organometallic halide perovskite nanocrystals. In the experiment, methylammonium lead bromide, CHNHPbBr, was efficiently doped with Cr cations by eco-friendly method at low temperatures to grow crystals antisolvent-crystallization. The as-synthesized Cr cation-doped perovskite nanocrystals displayed ∼45.
View Article and Find Full Text PDFDoping the SiO support with Co, Ni, Zn, and Sc improves the thermal conductivity of a hybrid PEG/SiO form-stable phase change material (PCM). Doping also improves the energy utilization efficiency and speeds up the charging and discharging rates. The thermal, chemical, and hydrothermal stability of the PEG/Zn-SiO and PEG/Sc-SiO hybrid materials is better than that of the other doped materials.
View Article and Find Full Text PDFTransition metal dichalcogenides (TMDCs)-based laminar membranes have gained significant interest in energy storage, fuel cell, gas separation, wastewater treatment, and desalination applications due to single layer structure, good functionality, high mechanical strength, and chemical resistivity. Herein, we review the recent efforts and development on TMDCs-based laminar membranes, and focus is given on their fabrication strategies. Further, TMDCs-based laminar membranes for water purification and seawater desalination are discussed in detail.
View Article and Find Full Text PDFIn this work, we report a facile synthesis of graphene oxide-gold (GO-Au) nanocomposites by electrodeposition. The fabricated electrochemical immunosensors are utilized for the dual detection of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) antigen and SARS-CoV-2 antibody. The GO-Au nanocomposites has been characterized by UV-vis spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), cyclic voltammetry (CV), differential pulse voltammetry (DPV), and electrochemical impedance spectroscopy (EIS) for its biosensing properties.
View Article and Find Full Text PDFThe performance of hybrid supercapacitors (HSCs) can be increased the selection of higher capacitive electrode materials. Thus, layered double hydroxides (LDHs) have received extensive consideration in HSCs owing to their good ion-exchange properties, structural flexibility, and large specific surface area. Ni-Co-based LDHs show better specific capacitance, good synergy, and high-rate capability in aqueous electrolytes.
View Article and Find Full Text PDFCenotes are habitats with unique physical, chemical, and biological features. Unexplored microorganisms from these sinkholes represent a potential source of bioactive molecules. Thus, a series of cultivable fungi ( spp.
View Article and Find Full Text PDFChemical investigation of strain HM1 (Punctulariaceae), a corticioid isolated from a decorticated piece of bark collected in Bosque de Tlalpan, Mexico City, led to the isolation of a new drimane, 1--hydroxy-isodrimenine (1: ) and a new tetrahydroxy kauranol, 16-hydroxy-phlebia--kauranol (2: ), together with the known -phenylacetamide (3: ). Structures of all compounds were elucidated by spectroscopic and spectrometric methods, and the absolute configuration of 1: and 2: was confirmed via single-crystal X-ray crystallography. The isolated compounds showed modest antimycobacterial activity.
View Article and Find Full Text PDFThe perovskites solar cells (PSCs) is composed of multifaceted device architecture and involve complex charge extraction (both electronic and ionic), this makes the task demanding to unlock the origin of the different physical process that occurs in a PSC. The capacitance in PSCs depends on several external perturbations including frequency, illumination, temperature, applied bias, and importantly on the interface modification of perovskites/charge selective contact. Arguably, different features including interfacial and bulk; ionic, and electronic charge transport in PSCs occur at different time scales.
View Article and Find Full Text PDFThe oxidation of transition metals such as manganese and copper by dioxygen (O) is of great interest to chemists and biochemists for fundamental and practical reasons. In this report, the O reactivities of 1:1 and 1:2 mixtures of [(TPP)Mn] (; TPP: Tetraphenylporphyrin) and [(tmpa)Cu(MeCN)] (; TMPA: Tris(2-pyridylmethyl)amine) in 2-methyltetrahydrofuran (MeTHF) are described. Variable-temperature (-110 °C to room temperature) absorption spectroscopic measurements support that, at low temperature, oxygenation of the (TPP)Mn/Cu mixtures leads to rapid formation of a cupric superoxo intermediate, [(tmpa)Cu(O)] (), independent of the presence of the manganese porphyrin complex ().
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