Dual Influence of Size and Electric Field on Gold Nanoparticles: Insights into 2D Monolayer Assembly.

Self-assembled gold nanoparticles (Au-NPs) possess distinctive properties that are highly desirable in diverse nanotechnological applications. This study meticulously explores the size-dependent behavior of Au-NPs under an electric field, specifically focusing on sizes ranging from 5 to 40 nm, and their subsequent assembly into 2D monolayers on an n-type silicon substrate. The primary objective is to refine the assembly process and augment the functional characteristics of the resultant nanostructures.

Gold on the horizon: unveiling the chemistry, applications and future prospects of 2D monolayers of gold nanoparticles (Au-NPs).

Noble 2D monolayers of gold nanoparticles (Au-NPs) have garnered significant attention due to their unique physicochemical properties, which are instrumental in various technological applications. This review delves into the intricate physical chemistry underlying the formation of Au-NP monolayers, highlighting key interactions such as electrostatic forces, van der Waals attractions, and ligand-mediated stabilization. The discussion extends to the size- and shape-dependent assembly processes of these NP monolayers, elucidating how nanoparticle dimensions and morphologies influence monolayer formation and stability.

Electric Field-Driven Self-Assembly of Gold Nanoparticle Monolayers on Silicon Substrates.

Nanoparticles (NPs) bridge the gap between bulk materials and their equivalent molecular/atomic counterparts. The physical, optical, and electronic properties of individual NPs alter with the changes in their surrounding environment at the nanoscale. Similarly, the characteristics of thin films of NPs depend on their lateral and volumetric densities.