Publications by authors named "Fioralba Taullaj"
An iridium complex with an unsupported Ir-Zn bond: di-iodido-(η-penta-methyl-cyclo-penta-dien-yl)bis-(tri-methyl-phosphane)iridiumzinc(-) benzene hemisolvate.
Acta Crystallogr E Crystallogr Commun
December 2019
The title compound, [IrZnI(CH)(CHP)]·0.5CH or [Cp*(PMe)Ir]-[ZnI] (Cp* = -CMe) was obtained and characterized as its benzene solvate [Cp*(PMe)Ir]-[ZnI]·0.5CH.
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- The study introduces new methods for creating 1- and 2-adamantyl anion equivalents using commercially available 1- and 2-adamantylzinc bromides and reducing metals like magnesium and lithium.
- Adamantylmagnesium bromides were successfully produced by reacting adamantylzinc bromides with excess magnesium, resulting in two new diadamantylzinc species that can be isolated without impurities.
- The generated adamantyl anions were then employed to generate novel adamantyl metal complexes, including the first unsupported 2-adamantyl metal complexes, with notable examples like 1- and 2-AdHg and 2-AdBiBr being isolated and structurally characterized.*