Competitive electron transfer in a novel, broad-band capturing, subphthalocyanine-AzaBODIPY-C60 supramolecular triad.

A V-configured subphthalocyanine-azaBODIPY-C60 supramolecular triad has been newly synthesized, and sequential energy and electron transfer leading to the formation of charge separated states, useful properties relevant for solar energy harvesting and building optoelectronic devices, is reported.

Multistep energy and electron transfer in a "V-configured" supramolecular BODIPY-azaBODIPY-fullerene triad: mimicry of photosynthetic antenna reaction-center events.

A new photosynthetic antenna-reaction-center model compound composed of covalently linked BF2 -chelated dipyrromethene (BODIPY), BF2 -chelated azadipyrromethene (azaBODIPY), and fullerene (C60 ), in a "V-configuration", has been newly synthesized and characterized by using a multistep synthetic procedure. Optical absorbance and steady-state fluorescence, computational, and electrochemical studies were systematically performed in nonpolar, toluene, and polar, benzonitrile, solvents to establish the molecular integrity of the triad and to construct an energy-level diagram revealing different photochemical events. The geometry obtained by B3LYP/6-31G* calculations revealed the anticipated V-configuration of the BODIPY-azaBODIPY-C60 triad.