We introduce NPKGRIDS, a new geospatial dataset, providing for the first time data on application rates for all three main plant nutrients, nitrogen (N), phosphorus (P, in terms of phosphorus pentoxide, PO) and potassium (K, in terms of potassium oxide, KO) across 173 crops as of 2020, with a geospatial resolution of 0.05° (approximately 5.6 km at the equator).
View Article and Find Full Text PDFHuman society is anchored in the global agroecosystem. For millennia, this system has provided humans with copious supplies of nutrient-rich food. Yet, through chemical intensification and simplification, vast shares of present-day farmland derive insufficient benefits from biodiversity and prove highly vulnerable to biotic stressors.
View Article and Find Full Text PDFCROPGRIDS is a comprehensive global geo-referenced dataset providing area information for 173 crops for the year 2020, at a resolution of 0.05° (about 5.6 km at the equator).
View Article and Find Full Text PDFPesticides are ubiquitous environmental pollutants negatively affecting ecosystem and human health. About 3 Tg of pesticides are used annually in agriculture to protect crops. How much of these pesticides remain on land and reach the aquifer or the ocean is uncertain.
View Article and Find Full Text PDFSci Total Environ
September 2022
Microplastic fibres are the most abundant microplastics in waterways worldwide. The settling of fibres is distinct from other particles because of their aspect ratio and shape. In this paper, we test the hypothesis that length, curliness, and settling orientation control the settling velocity of microplastic fibres in a suite of laboratory experiments.
View Article and Find Full Text PDFWe introduce here SOIL-WATERGRIDS, a new dataset of dynamic changes in soil moisture and depth of water table over 45 years from 1970 to 2014 globally resolved at 0.25 × 0.25 degree resolution (about 30 × 30 km at the equator) along a 56 m deep soil profile.
View Article and Find Full Text PDFWhile the use of pesticides continues to rise worldwide, our understanding of the pervasiveness of associated contamination and the health risks humans may be exposed to remain limited to small samples size, and based on small geographic scales, the exposed population, or the pesticide types. Using our recent mapping of global pesticide use, we quantify three complementary health risk metrics for 92 active ingredients: (i) the pesticide hazard load (PHL); (ii) the population exposure (PE); and (iii) the human intake relative to the acceptable dose (INTR). We integrated these metrics into the pesticide health risk index (PHRI) to assess the standing of 133 nations against the global averages of PHL and PE and the acceptable levels of INTR using data of 2015 (PHRI > 1 indicates a concern).
View Article and Find Full Text PDFTrifluralin is a widely used dinitroaniline herbicide, which can persist in the environment and has substantial ecotoxicity, especially to aquatic organisms. Trifluralin is very insoluble in water (0.22 mg/L at 20 °C) and highly volatile (vapor pressure of 6.
View Article and Find Full Text PDFAgricultural pesticides can become persistent environmental pollutants. Among many, glyphosate (GLP) is under particular scrutiny because of its extensive use and its alleged threats to the ecosystem and human health. Here, we introduce the first global environmental contamination analysis of GLP and its metabolite, AMPA, conducted with a mechanistic dynamic model at 0.
View Article and Find Full Text PDFDegraded plastic debris has been found in nearly all waters within and nearby urban developments as well as in the open oceans. Natural removal of suspended microplastics (MPs) by deposition is often limited by their excess buoyancy relative to water, but this can change with the attachment of biological matter. The extent to which the attached biological ballast affects MP dynamics is still not well characterised.
View Article and Find Full Text PDFAvailable georeferenced environmental layers are facilitating new insights into global environmental assets and their vulnerability to anthropogenic inputs. Geographically gridded data of agricultural pesticides are crucial to assess human and ecosystem exposure to potential and recognised toxicants. However, pesticides inventories are often sparse over time and by region, mostly report aggregated classes of active ingredients, and are generally fragmented across local or government authorities, thus hampering an integrated global analysis of pesticide risk.
View Article and Find Full Text PDFGlyphosate (GLP) is one of the most widely-used herbicides globally and its toxicity to humans and the environment is controversial. GLP is biodegradable, but little is known about the importance of site exposure history and other environmental variables on the rate and pathway of biodegradation. Here, GLP was added to microcosms of soils and sediments with different exposure histories and these were incubated with amendments of glucose, ammonium, and phosphate.
View Article and Find Full Text PDFBiodegradation of glyphosate (GLP) and its metabolite aminomethylphosphonic acid (AMPA) was numerically assessed for a vineyard and a wheat field in the Po Valley, Italy. Calculation of the Hazard Quotient suggested that GLP and AMPA can pose a risk of aquifer contamination in the top 1.5 m depth within 50 years of GLP use.
View Article and Find Full Text PDFThe genesis of suspended aggregates in aquatic ecosystems is not only a result of hydrodynamic mineral interactions but also a complex microbial food web network. A microbiological-physical model (BFLOC2) is introduced here to predict aggregate geometry and settling velocity under simultaneous effects of hydrodynamic and biological processes. While minerals can contribute to aggregate dynamics through collision, aggregation, and breakup, living microorganisms can colonize and establish food web interactions that involve growth and grazing, and modify the aggregate structure.
View Article and Find Full Text PDFA soil-based cropping unit fuelled with human urine for long-term manned space missions was investigated with the aim to analyze whether a closed-loop nutrient cycle from human liquid wastes was achievable. Its ecohydrology and biogeochemistry were analysed in microgravity with the use of an advanced computational tool. Urine from the crew was used to supply primary (N, P, and K) and secondary (S, Ca and Mg) nutrients to wheat and soybean plants in the controlled cropping unit.
View Article and Find Full Text PDFThe detection of microbial colonization in geophysical systems is becoming of interest in various disciplines of Earth and planetary sciences, including microbial ecology, biogeochemistry, geomicrobiology, and astrobiology. Microorganisms are often observed to colonize mineral surfaces, modify the reactivity of minerals either through the attachment of their own biomass or the glueing of mineral particles with their mucilaginous metabolites, and alter both the physical and chemical components of a geophysical system. Here, we hypothesise that microorganisms engineer their habitat, causing a substantial change to the information content embedded in geophysical measures (e.
View Article and Find Full Text PDFAn experimental study was conducted to test the hypothesis that the biomass growing after an increase in available nutrient in an aquatic ecosystem affects the flocculation dynamics of suspended particulate matter (SPM). The experiment was carried out in a settling column equipped with a turbulence generating system, a water quality monitoring system, and an automated μPIV system to acquire micro photographs of SPM. Three SPM types were tested combinatorially at five turbulence shear rates, three nutrient concentrations, and three mineral concentrations.
View Article and Find Full Text PDFThere has been growing interest in using the fractal dimension to study the hierarchical structures of soft materials after realising that fractality is an important property of natural and engineered materials. This work presents a method to quantify the internal architecture and the space-filling capacity of granular fractal aggregates by reconstructing the three-dimensional capacity dimension from their two-dimensional optical projections. Use is made of the light intensity of the two-dimensional aggregate images to describe the aggregate surface asperities (quantified by the perimeter-based fractal dimension) and the internal architecture (quantified by the capacity dimension) within a mathematical framework.
View Article and Find Full Text PDFAn approach based on spheropolygons (i.e., the Minkowski sum of a polygon with N vertices and a disk with spheroradius r) is presented to describe the shape of kaolinite aggregates in water and to investigate interparticle collision dynamics.
View Article and Find Full Text PDFRapid Commun Mass Spectrom
February 2012
Rationale: Earlier experiments demonstrated that isotopic effects during nitrification, denitrification and dissimilatory nitrate reduction can be affected by high (15) N contents. These findings call into question whether the reaction parameters (rate constants and Michaelis-Menten concentrations) are function of δ(15) N values, and if these can also lead to significant effects on the bulk reaction rate.
Methods: Five experiments at initial δ(15) N-NO(3) (-) values ranging from 0‰ to 1700‰ were carried out in a recent study using elemental analyser, gas chromatography, and mass spectrometry techniques coupled at various levels.