Arthroscopic versus open treatment of cam-type femoro-acetabular impingement: retrospective cohort clinical study.

Purpose: The purpose of this study was to determine if there were significant differences between patients submitted to hip arthroscopy (HA) and surgical hip dislocation (SHD) to treat femoro-acetabular impingement (FAI), which variables were significantly associated with hip function before surgery and those predictive of the applied functional outcome scale and its variation rate after surgery.

Methods: We selected 198 patients treated with HA or SHD with a mean follow-up of 59 months. Inclusion criteria were ages 18-50 years, isolated FAI cam morphology and complete clinical and radiologic documentation.

Mixtures of the 1-ethyl-3-methylimidazolium acetate ionic liquid with different inorganic salts: insights into their interactions.

In this work, we explore the interactions between the ionic liquid 1-ethyl-3-methylimidazolim acetate and different inorganic salts belonging to two different cation families, those based on ammonium and others based on sodium. NMR and Raman spectroscopy are used to screen for changes in the molecular environment of the ions in the ionic liquid + inorganic salt mixtures as compared to pure ionic liquid. The ion self-diffusion coefficients are determined from NMR data, allowing the discussion of the ionicity values of the ionic liquid + inorganic salt mixtures calculated using different methods.

Morphologic and angular planning for cam resection in femoro-acetabular impingement: value of the omega angle.

Purpose: The alpha angle is used to quantify in a single plane the head-neck junction deformity of cam femoro-acetabular impingement (FAI). When the deformity overlaps the superior retinaculum, femoral head osteoplasty in this area can jeopardise intra-articular vascular structures. This study proposes a new angular measure of the linear radial extension of cam deformity as a planning tool for bone resection and compares the accuracy of femoral head osteoplasty using open and arthroscopic surgery.

High ionicity ionic liquids (HIILs): comparing the effect of ethylsulfonate and ethylsulfate anions.

The subject of ionicity has been extensively discussed in the last decade, due to the importance of understanding the thermodynamic and thermophysical behaviour of ionic liquids. In our previous work, we established that ionic liquids' ionicity could be improved by the dissolution of simple inorganic salts in their milieu. In this work, a comparison between the thermophysical properties of two binary systems of ionic liquid + inorganic salt is presented.

Synthesis, characterization, and liposome partition of a novel tetracycline derivative using the ionic liquids framework.

Recently, efforts have been put on the development of new drug formulations using ionic liquid framework. In this work, two different species of abroad-spectrum polyketide antibiotic, tetracycline, are studied in terms of some important properties for antibiotics such as solubility in water and hydrophilic-hydrophobic balance. Tetracycline was used as cation, whereas docusate, a biocompatible anion, which enables the tailoring of the hydrophilicity of salts, was chosen as the anion.

Inorganic salts in purely ionic liquid media: the development of High Ionicity Ionic Liquids (HIILs).

This work explores the possibility of increasing the ionicity of ionic liquids via the solubilization of inorganic salts in their midst. The resulting purely ionic media-distinct ionic liquid plus inorganic salt mixtures-are liquid in an extensive concentration range and can be aptly denominated High Ionicity Ionic Liquids (HIILs).