Using Nitroxides to Enhance Carbon Fiber Interfacial Adhesion and as an Anchor for "Graft to" Surface Modification Strategies.

Nitroxide groups covalently grafted to carbon fibers are used as anchoring sites for TEMPO-terminated polymers (poly-n-butylacrylate and polystyrene) in a "graft to" surface modification strategy. All surface-modified fibers are evaluated for their physical properties, showing that several treatments have enhanced the tensile strength and Young's modulus compared to the control fibers. Up to an 18% increase in tensile strength and 12% in Young's modulus are observed.

Peptide-Driven Exfoliation and Dispersion Mechanisms of Graphene in Aqueous Media.

Peptide-mediated exfoliation and suspension of graphene in aqueous media is a promising strategy for bioapplications such as drug delivery, tissue engineering, and biosensors. A few peptide sequences are known as graphene exfoliators/dispersants in water, but the mechanisms underpinning this process remain underexplored. Here, molecular simulations investigate two key steps: sheet exfoliation and subsequent sheet reunification, in aqueous media.

Moisture Ingress at the Molecular Scale in Hygrothermal Aging of Fiber-Epoxy Interfaces.

Almost all applications of carbon fiber reinforced composites are susceptible to water aging, either via ambient humidity or through direct exposure to liquid water environments. Although the impacts of water aging in composites can be readily quantified via experimental efforts, details regarding the mechanisms of moisture ingress and aging, particularly at the incipient stages of aging under hygrothermal conditions, have proven challenging to resolve using experimental techniques alone. A deeper understanding of the factors that drive incipient moisture ingress during aging is required for more targeted approaches to combat water aging.