Amorphous K-Co-Mo-S Chalcogel: A Synergy of Surface Sorption and Ion-Exchange.

Chalcogel represents a unique class of meso- to macroporous nanomaterials that offer applications in energy and environmental pursuits. Here, the synthesis of an ion-exchangeable amorphous chalcogel using a nominal composition of KCoMoS (KCMS) at room temperature is reported. Synchrotron X-ray pair distribution function (PDF), X-ray absorption near-edge structure (XANES), and extended X-ray absorption fine structure (EXAFS) reveal a plausible local structure of KCMS gel consisting of Mo and Mo clusters in the vicinity of di/polysulfides which are covalently linked by Co ions.

Light-Induced Wavelength Dependent Self Assembly Process for Targeted Synthesis of Phase Stable 1D Nanobelts and 2D Nanoplatelets of CsPbI Perovskites.

Despite black cubic phase α-CsPbI nanocrystals having an ideal bandgap of 1.73 eV for optoelectronic applications, the phase transition from α-CsPbI to non-perovskite yellow δ-CsPbI phase at room temperature remains a major obstacle for commercial applications. Since γ-CsPbI is thermodynamically stable with a bandgap of 1.

WO Nanowire-Attached Reduced Graphene Oxide-Based 1D-2D Heterostructures for Near-Infrared Light-Driven Synergistic Photocatalytic and Photothermal Inactivation of Multidrug-Resistant Superbugs.

The rapid emergence of superbugs which are resistant to existing antibiotics is becoming a huge global threat to public health, which demands the discovery of next-generation antibacterial agents for combating superbugs. Herein, we report the design of a two-dimensional (2D) reduced graphene oxide (r-GO) and one-dimensional (1D) WO nanowire-based photothermal-photocatalytic heterostructure for combating multiantibiotic-resistant DT104, carbapenem-resistant , and methicillin-resistant superbugs. In the presence of near-infrared (NIR) light, due to the generation of electrons and holes, the WO-based heterostructure generates reactive oxygen species by photocatalytic reaction from water and oxygen, which kills superbugs.

Horizontal and Vertical Transport of Uranium in an Arid Weapon-Tested Ecosystem.

Armor-penetrating projectiles and fragments of depleted uranium (DU) have been deposited in soils at weapon-tested sites. Soil samples from these military facilities were analyzed by inductively coupled plasma-optical emission spectroscopy and X-ray diffraction to determine U concentrations and transport across an arid ecosystem. Under arid conditions, both vertical transport driven by evaporation (upward) and leaching (downward) and horizontal transport of U driven by surface runoff in the summer were observed.

Effect of humic acid derived from leonardite on the redistribution of uranium fractions in soil.

Humic acids (HAs) are complex organic substances with abundant functional groups (, carboxyl, phenolic-OH, .). They are commonly distributed in the soil environment and exert a double-edged sword effect in controlling the migration and transformation of uranium.

Indigenous earthworms and gut bacteria are superior to chemical amendments in the remediation of cadmium-contaminated seleniferous soils.

The natural selenium (Se)-rich areas in China are generally characterized by high geological background of cadmium (Cd) which poses potential risks to human health. Therefore, immobilization of Cd is the prerequisite to ensure the safe utilization of natural seleniferous soil resources. A pot experiment was conducted to compare the effects of indigenous earthworm (Amynthas hupeiensis) and its gut bacteria (Citrobacter freundii DS strain) on the remediation of Cd-contaminated seleniferous soil with two traditional chemical amendments.

Developing a novel computer visualization system to simulate the uranium upward transport mechanism: Uranium pollution in arid landscapes.

Uranium (U) is a naturally occurring, radioactive, toxic trace element that poses severe risks to public and environmental health. Depleted uranium (DU) is widely used in military munitions, including penetrators. Our previous studies showed that in arid landscapes, water-soluble U released from corroded DU penetrators that were buried underground were co-transported upwards with water by evaporation-driven capillary action and eventually precipitated on the ground surface.

A laboratory preparation procedure for studying bioaccumulation of U and its subcellular form in earthworms ( spp.).

Uranium (U) is a ubiquitous trace element in soils. With increasing in application of U in nuclear energy and nuclear weapon, a large amount of U was dissipated into the environment including soil and water. Earthworm may be an eco-indicator for U bioaccumulation, transformation and transport across the ecosystem.

Universal Surface Passivation of Organic-Inorganic Halide Perovskite Films by Tetraoctylammonium Chloride for High-Performance and Stable Perovskite Solar Cells.

The power conversion efficiency (PCE) of perovskite solar cells has been showing rapid improvement in the last decade. However, still, there is an unarguable performance deficit compared with the Schockley-Queisser (SQ) limit. One of the major causes for such performance discrepancy is surface and grain boundary defects.

Removal of CrO, a Nonradioactive Surrogate of TcO, Using LDH-MoS Nanosheets.

Removal of chromate (CrO) and pertechnetate (TcO) from the Hanford Low Activity Waste (LAW) is beneficial as it impacts the cost, life cycle, operational complexity of the Waste Treatment and Immobilization Plant (WTP), and integrity of vitrified glass for nuclear waste disposal. Here, we report the application of [MoS] intercalated layer double hydroxides (LDH-MoS) for the removal of CrO as a surrogate for TcO, from ppm to ppb levels from water and a simulated LAW off-gas condensate of Hanford's WTP. LDH-MoS removes CrO from the LAW condensate stream, having a pH of 7.

Silicon enhances abundances of reducing microbes in rhizoplane and decreases arsenite uptake by rice (Oryza sativa L.).

Although silicon (Si) transporters-mediated uptake of arsenic (As) by rice roots is well-documented, how Si influences As behaviors in rhizosphere and rhizoplane before As entry into roots is still unclear. Here we used three rice genotypes to explore the effect of silicic acid on the root uptake of As as impacted by chemical and microbial changes in bulk soil, rhizosphere, rhizoplane and endosphere. The results show that exogenous Si decreased root arsenite [As(III)] absorption, which was attributed to Si-mediated alteration of traits in chemical plaque and microbial films on the rhizoplane.

A comparative study on adsorption of cadmium and lead by hydrochars and biochars derived from rice husk and Zizania latifolia straw.

In this study, hydrochars and biochars were prepared from rice husk (RH) and Zizania latifolia straw (ZL) at various pyrolysis temperatures as absorbents, for removing toxic ions from single and competitive solutions of cadmium (Cd) and/or lead (Pb). The adsorption efficiencies of Cd and Pb in both hydrochars and biochars were lower in the competitive solution than in the single solution, and the absorbents had a stronger affinity for Pb than for Cd. Compared to hydrochars, biochars showed more favorable Cd and Pb adsorption capacities in the single or competitive solutions, and the ZL biochars had the maximum adsorption capacity among them.

A laboratory simulation to investigate effects of moistures on U distribution among solid phase components in army range soils.

Uranium is a naturally occurring radioactive trace element found in rocks, soils, and coals. U may contaminate groundwater and soil from nuclear power plant operations, spent fuel reprocessing, high-level waste disposal, ore mining and processing, or manufacturing processes. Yuma Proving Ground in Arizona, USA has been used depleted uranium ballistics for 36 years where U has accumulated in this army testing site.

Migration and Removal of Labile Cadmium Contaminants in Paddy Soils by Electrokinetic Remediation without Changing Soil pH.

Electrokinetic remediation (EKR) is a viable, advanced cleaning strategy that can permanently reduce the toxicity of soil contaminants. However, EKR is prone to causing changes in soil pH. The negative impacts must be minimized if field-scale application is to be realized.

The Adsorption Characteristics of Uranium(VI) from Aqueous Solution on Leonardite and Leonardite-Derived Humic Acid: A Comparative Study.

The humic substance is a low-cost and effective adsorbent with abundant functional groups in remediating uranium (U) (VI)-contaminated water. In this research study, leonardite together with leonardite-derived humic acid (L-HA) was used to eliminate U(VI) from water under diverse temperatures (298, 308, and 318 K). L-HA showed a higher adsorption volume for U(VI) than leonardite.

Functionalization of clay surface for the removal of uranium from water.

A modification method of clay mineral surface was developed to improve its adsorption capacity of uranium. Uranium is a radionuclide with high toxicity and extremely long half-life, which can pollute the environment and endanger human health. This study proposes a new method of activation of clay mineral surface with phosphoric acid for rapid adsorption of uranium from aqueous solution.

A simple method for the synthesis of biochar nanodots using hydrothermal reactor.

Biochar is a stable carbon rich by-product synthesized through pyrolysis of plant and animal based biomass, and nano-biochar material has gained increasing attention due to its unique properties for environmental applications. In the present study, a simple cost-effective method for the synthesis of biochar nanoparticles through hydrothermally using agricultural residuals and by-products was developed. Both soybean straw and cattle manure were selected as the feedstock to produce the bulk-biochar.

Continuous growth phenomenon for direct synthesis of monodisperse water-soluble iron oxide nanoparticles with extraordinarily high relaxivity.

The direct synthesis of highly water-soluble nanoparticles has attracted intensive interest, but systematic size control has not been reported. Here, we developed a general method for synthesizing monodisperse water-soluble iron oxide nanoparticles with nanometer-scale size increments from 4 nm to 13 nm in a single reaction. Precise size control was achieved by continuous growth in an amphiphilic solvent, diethylene glycol (DEG), where the growth step was separated from the nucleation step by sequential addition of a reactant.

Laboratory simulation of uranium metal corrosion in different soil moisture regimes.

A novel laboratory simulation system has been developed for the study of the corrosion of uranium metal in soils. Corrosion and transportation of depleted uranium (DU) as the metal undergoes weathering as a buried material within the soil environment. The corrosion of uranium metal in soil was not well understood due to the gas-liquid-solid phase of the soil.

A novel laboratory simulation system to uncover the mechanisms of uranium upward transport in a desert landscape.

After depleted uranium (DU) is deposited in the environment, it corrodes producing mobile uranium species. The upward transport mechanism in a desert landscape is associated with the dissolution/precipitation of uranium minerals that vary in composition and solubility in soil pore water. The objective of this study is to develop the laboratory column simulation to investigate the upward transport mechanism with cyclic capillary wetting and drying moisture regimes.

Assessment of the immobilization effectiveness of several amendments on a cadmium-contaminated soil using Eisenia fetida.

Proper protocols for assessing the remediation effectiveness of contaminated soils are an important part of remediation projects. In the present study, the residual immobilization effectiveness of hydrated lime (L), hydroxyapatite (H), biochar (B) and organic fertilizer (F) alone and in combination was assessed by Eisenia fetida. The results showed that the application of amendments had no significant effect on the death rate and average fresh weight loss of earthworms.

Effects of Vegetable Fields on the Spatial Distribution Patterns of Metal(loid)s in Soils Based on GIS and Moran's I.

Metal(loid) pollution in vegetable field soils has become increasingly severe and affects the safety of vegetable crops. Research in China has mainly focused on greenhouse vegetables (GV), while open field vegetables (OV) and the spatial distribution patterns of metal(loid)s in the surrounding soils have rarely been assessed. In the present study, spatial analysis methods combining Geographic Information Systems (GIS) and Moran's I were applied to analyze the effects of vegetable fields on metal(loid) accumulation in soils.

Designing Highly Crystalline Multifunctional Multicolor Luminescence Nanosystem for Tracking Breast Cancer Heterogeneity.

Breast tumor heterogeneity is responsible for the death of ~ 40,000 women in 2017 in USA. Triple-negative breast cancers (TNBCs) are very aggressive and it is the only breast cancer subgroup still lacking effective therapeutic. As a result, early stage detection of TNBC is vital and it will have huge significant in the clinics.