Enhancive and inhibitory effects of copper complexation on triplet dissolved black carbon-sensitized photodegradation of organic micropollutants.

Excited-triplet dissolved black carbon (DBC) was deemed as a significant reactive intermediate in the phototransformation of environmental micropollutants, but the impacts of concomitant metal ions on photochemical behavior of excited-triplet DBC (DBC*) are poorly understood. Here, the photolytic kinetics of sulfadiazine and carbamazepine induced by DBC* involving Cu was explored. The presence of Cu reduced the DBC*-induced photodegradation rate of sulfadiazine; whereas for carbamazepine, Cu enhanced DBC*-induced photodegradation.

[Photo-assisted Degradation of Sulfamethazine by Ferrocene-catalyzed Heterogeneous Fenton-like System].

Antibiotics are acknowledged micropollutants in wastewaters and surface waters. They are of particular concern because they can trigger an increase in resistant bacteria. Therefore, novel and efficient technology for the removal of antibiotics is urgently needed.

Fluorescent pH Sensors for Broad-Range pH Measurement Based on a Single Fluorophore.

We constructed a series of novel optical sensors for determination of broad-range pH based on a single fluorophore and multi-ionophores with different pK(a) values. These optical sensors use photoinduced electron transfer (PET) as the signal transduction and follow the design concept of "fluorophore-spacer-receptor (ionophore)" which employs 4-amino-1,8-naphthalimide as the single fluorophore, ethyl moiety as the spacer, and a series of phenols and anilines as the receptors. Key to the successful development of this sensor system is that coupling the receptors with six different pK(a) values with a single fluorophore produces the correct optical properties.