According to the emission characteristics of volatile organic compounds (VOCs) in the petrochemical plants of China, the storage stability of VOCs for two different bags, polyester aluminum (PEA) and polyvinyl fluoride (PVF), was investigated in this study by comparing the adsorption of gas samples. A series of experiments were carried out to study the impact of different factors of sampling in the petrochemical industry. The results showed that the C2∼C3 substances can be adsorbed by the Tedlar bag, and after being refilled with pure nitrogen, the VOCs adsorbed previously by the bag material can be released.
View Article and Find Full Text PDFSoil thermal state exerts an important role in soil physicochemical properties, nutrient content, soil carbon losses, and hydrological processes in cold regions. In the Qinghai-Tibet Plateau, desertification and aeolian sand accumulation greatly change the surface cover types and simultaneously alter the surface energy budget. However, the quantification of their impacts on the soil thermal state hasn't been studied methodically.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
March 2020
The toluene poses a serious threat to the atmospheric environment and human health. Herein, the reduced graphene oxide (rGO)/TiO immobilized on the activated carbon fiber (ACF) are fabricated by ultrasonic assisted sol-gel impregnation method to photodegrade dynamic toluene. Characterizations of rGO/TiO/ACF composites reveal that the majority of graphene oxide (GO) is reduced to rGO and rGO/TiO is evenly loaded onto the ACF surface in the form of a smooth film.
View Article and Find Full Text PDFStorage tanks are important parts of volatile organic compound (VOC) fugitive emission sources of the petrochemical industry; the floating roof tank is the main oil storage facility at present. Based on the mechanism of withdrawal loss and the type of rim seal, octane and gasoline were taken as the research objects. A model instrument for simulating the oil loading process by the 316 stainless steel and A3 carbon steel as the test piece was designed, and the film thickness was measured by wet film thickness gauge to investigate the influence of the corrosion of the tank wall and rim seal on the withdrawal loss for floating roof tanks.
View Article and Find Full Text PDFThe concentration of propofol in patient's exhaled air is an indicator of the anesthetic depth. In the present study, a membrane inlet ion mobility spectrometer (MI-IMS) was built for the on-line measurement of propofol. Compared with the direct sample introduction, the membrane inlet could eliminate the interference of moisture and improve the selectivity of propofol.
View Article and Find Full Text PDFIon mobility spectrometry (IMS) is an attractive detector of gas chromatography (GC) due to its high sensitivity, short response time, and comparatively low cost. The hyphenated GC-IMS instrument can simultaneously provide high separation ability of GC and high sensitivity of IMS. In this paper, one setup of a GC-IMS instrument is introduced.
View Article and Find Full Text PDFA less laborious, structure-simple, and performance-reliable printed circuit board (PCB) based Bradbury-Nielsen gate for high-resolution ion mobility spectrometry was introduced and investigated. The gate substrate was manufactured using a PCB etching process with small holes (Φ 0.1 mm) drilled along the gold-plated copper lines.
View Article and Find Full Text PDFA novel bipolar ionization source based on a commercial vacuum-UV Kr lamp has been developed for ion mobility spectrometry (IMS), which can work in both negative and positive ion mode. Its reactant ions formed in negative ion mode were predominantly assigned to be O(3)(-)(H(2)O)(n), which is different from that of the (63)Ni source with purified air as carrier and drift gases. The formation of O(3)(-)(H(2)O)(n) was due to the production of ozone caused by ultraviolet radiation, and the ozone concentration was measured to be about 1700 ppmv by iodometric titration method.
View Article and Find Full Text PDF