High-efficiency oxygen evolution on γ-FeO catalysts with BiVO photoabsorbers and TpAQ hole transport layers for photoelectrochemical water splitting.

The interfacial energy levels between oxygen-excavating co-catalysts (OECs) and BiVO often lead to carrier recombination. Modulating the interface using a hole transport layer (HTL) can effectively inhibit interfacial recombination, realizing efficient photoelectrochemical (PEC) water splitting. Herein, we design BiVO@γ-FeO/TpAQ photoanodes by one-step solvothermal insertion of TpAQ COF between BiVO and γ-FeO co-catalysts as HTL layer.

[Bioaccumulation and Translocation Characteristics of Heavy Metals in a Soil-Maize System in Reclaimed Land and Surrounding Areas of Typical Vanadium-Titanium Magnetite Tailings].

A total of 86 soil samples, 86 corn kernel samples, 50 tailings samples, and 33 ore rock samples were collected in reclaimed land and surrounding areas of typical vanadium-titanium magnetite tailings located in the Chengde Central Region and analyzed for 14 elements (P, Fe, Cu, Ni, Cd, Cr, Pb, Zn, Hg, Ti, Mn, and Mo) and speciation of heavy metals. This study investigated the bioaccumulation and translocation characteristics of heavy metals in a soil-maize system based on a descriptive statistical analysis, a geological accumulative index, bioconcentration factors, and a redundancy analysis. The results showed that the average accumulation index of surface soil followed an order of P > Cu > FeO > Cr > Ti > V > Ni > Mn > Cd > Zn > Mo > As > Pb > Hg, while the accumulation level of heavy metals was generally categorized as either no accumulation or moderate accumulation.

[Source of Groundwater Nitrate in Luanping Basin Based on Multi-environment Media Nitrogen Cycle and Isotopes].

The multi-environment media of water, surface soil and vadose zone soil samples were collected in the upstream of Miyun Reservoir, in the Luanping Basin of Chengde City, Hebei Province. The aim was to identify the pollution source, ratio, spatial distribution, migration, and transformation characteristics of nitrogen in groundwater. Hydrogeochemistry, soil total nitrogen, and dissolved nitrate nitrogen of vadose zone soil analysis and a multi isotope tracer technique of N-NO and O-NO, S-SO and O-SO, C, combined with land-use type analysis and geostatistics, were used in the study.

[Determination of Heavy Metal Geochemical Baseline Values and Its Accumulation in Soils of the Luanhe River Basin, Chengde].

A total of 351 surface soil samples (0-20 cm) were collected from the Luanhe River Basin in Chengde City (a typical area of concentrated mineral resources) and analyzed for 12 heavy metals (Cu, Ni, Cd, Cr, Pb, Zn, Hg, V, Ti, Mn, As, and Co). The geochemical baseline values of the heavy metals were determined using the reference element method and the cumulative frequency curve method. Furthermore, the spatial structure and distribution characteristics of the heavy metals were assessed based on PCA and geostatistical analysis.

Rare allele of HvLox-1 associated with lipoxygenase activity in barley (Hordeum vulgare L.).

Identification and allele-specific marker development of a functional SNP of HvLox - 1 which associated with barley lipoxygenase activity. Improving the stability of the flavor of beer is one of the main objectives in breeding barley for malting, and lipoxygenase-1 (LOX-1) is a key enzyme controlling this trait. In this study, a modified LOX activity assay was used for null LOX-1 mutant screening.