Paper-based packaging materials have gained attention from academia and industry for their outstanding environmental sustainability advantages. However, they still encounter major challenges, such as low mechanical strength and inadequate functionality, hindering the replacement of unsustainable packaging materials. Inspired by the remarkable strength of trees provided by cellulose fibers and the water and heat protection of trees provided by bark, this study developed a new biomass-based packaging material (SNC-C) that combines strength, thermal insulation, and water resistance.
View Article and Find Full Text PDFThe use of natural starch as a replacement for petroleum-based packaging materials is limited due to its poor processability, weak mechanical properties, and strong moisture sensitivity. To address these limitations, this study adopts molecular design of hydroxypropylation and acetylation to sequentially modify natural starch, and material design of introducing acetylated cellulose nanofibers (ACNF) into the starch matrix to reinforce the material. Hydroxypropylation decreased the interaction force between the starch molecular chains, thereby reducing the glass transition temperature.
View Article and Find Full Text PDFUnder a global carbon-neutralizing environment, renewable wood is a viable alternative to non-renewable resources due to its abundance and high specific strength. However, fast-growing wood is hard to be applied extensively due to low mechanical strength and poor dimensional stability and durability. In this study, epoxy-acrylic resin-modified wood was prepared by forming a functional monomer system with three monomers [glycidyl methacrylate (GMA), maleic anhydride (MAN), and polyethylene glycol-200-dimethylacrylic acid (PEGDMA)] and filling into the wood cell cavity.
View Article and Find Full Text PDFWaterborne polyurethane coatings (WPU) are widely used in various types of coatings due to their environmental friendliness, rich gloss, and strong adhesion. However, their inferior mechanical properties and solvent resistance limit their application on the surface of wood products. In this study, graphene oxide (GO) with nanoscale size, large surface area, and abundant functional groups was incorporated into WPU by chemical grafting to improve the dispersion of GO in WPU, resulting in excellent mechanical properties and solvent resistance of WPU coatings.
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