[Synthesis, characterization and fluorescent property of terbium binary and ternary complexes with p-aminohippuric acid].

A series of binary and ternary rare-earth compounds were synthesized by the reaction of terbium ion with p-aminohippuric (PAH, HL) acid and phenanthroline (phen) or 2,2'-bipyridine(2,2'-bpy) in the ethanol solution. The compositions of the complexes were deduced to be TbL3(1), TbL3.phen.

Targeted self-assembly and quantum Monte Carlo magnetic study of an alternating nickel(II) 1D coordination polymer composed of highly preorganized binuclear tectons.

A pyrazolate-based binucleating ligand HL with pyridyl groups in the chelate arms has been used to synthesize the dinickel(II) complex [LNi2(N3)(MeOH)2](ClO4)2 (1) and the corresponding 1D polymeric [LNi2(mu-N3)2]n(NO3)n (2) depending on the amount of NaN3 added. X-Ray crystallography shows that structural parameters of the (LNi2(N3)) units are very similar in both compounds. This is ascribed to pi-pi stacking between the pyridyl rings that leads to rigidification of the framework and a fixed cis-orientation of the remaining coordination sites, which are filled by MeOH molecules in or by a mu1,3-bridging azide that connects the subunits in 2.

[Synthesis and spectral characterization of rare-earth-3-hydroxyl-2-naphthalinate-phenanthroline compounds].

The solid rare-earth (RE=Tb, Eu, Sm, Nd) compounds with 3-hydroxyl-2-naphthalinic acid (L) and phenanthroline (phen) were synthesized in ethanol solution in the present work. Their compositions were determined to be REL4 x phen2 x Na x H2O by the element analysis, infrared and ultraviolet absorption spectra, and DTA-TGA, respectively. The spectral properties of the compounds were studied tentatively, and the coordination mode of carboxyl group was deduced to be bridged style to chelate the rare-earth and sodium ions to form an infinite chain structural complex.

[Synthesis and spectral characterization of rare-earth-ortho-amino phenylbenzoate-2,2'-bipyridine complexes].

The solid rare-earth complexes were synthesized using rare-earth ions (RE=Tb, Nd, Sm, La) reacting with ortho-amino phenylbenzoic acid (L) and 2,2'-bipyridine (bipy). Their compositions were confirmed and the spectral properties were characterized by element analysis, infrared and ultraviolet absorption spectra, and DTA-TGA. The fluorescent properties of complexes TbL3 and TbL3 x bipy x 3H2O were also measured and discussed.

[Synthesis, characterization and fluorescent property of ternary complexes of rare-earth, cinnamic acid and 2,2'-bipyridine].

The ternary rare-earth complexes were synthesized using cinnamic acid (L), 2,2'-bipyridine (bipy) and rare-earth (RE= Tb, Eu, Gd, Nd) in ethanol solution. Their compositions were confirmed to be REL3 x bipy by the element analysis, infrared and ultraviolet absorption spectra, and DTA-TGA, respectively. The spectral properties of complexes and the fluorescent property of EuL3 x bipy were discussed.

[Synthesis and fluorescence property of complexes of rare-earth with p-nitrophenylacetic acid].

The binary solid complexes had been synthesized using rare-earth ion with p-nitrophenylacetic acid. The chemical formula of ReL3.H2O(Re = Eu, Sm, Tb) complexes was determined by elemental analysis, molar conductivity, and TG-DTA.