Surface plasmon resonance (SPR) is demonstrated in a microstructured optical fiber sensor for the first time (to our knowledge). SPR features were observed at 560 and 620 nm when sample fluids of refractive indices n=1.38 and n=1.
View Article and Find Full Text PDFNuclear magnetic resonance was used to probe the distribution of water and ionic species in a microstructured poly(methyl methacrylate) (PMMA) polymer optical fiber (MPOF), with a plan to assess the suitability of these fibers for aqueous chemosensing. The NMR spectra and the measurements of proton spin relaxation in hydrated fibers demonstrated the presence of two distinct pools of water: water residing in the microstructure channels and the hydration water residing in the polymer matrix of the fiber. No facile chemical exchange between these two pools was present.
View Article and Find Full Text PDFImprovement of surface enhanced resonant Raman scattering (SERRS) signals is demonstrated by confining the scattering event to the core of a hollow core microstructured optical fiber. The analyte solution fills the entire microstructure. The pump light is guided in the liquid core and the Raman scattered signal is efficiently collected by the fiber and transmitted to the detector.
View Article and Find Full Text PDFA unique optical fibre design is presented in this work: a laterally accessible microstructured optical fibre, in which one of the cladding holes is open to the surrounding environment and the waveguide core exposed over long lengths of fibre. Such a fibre offers the opportunity of real-time chemical sensing and biosensing not previously possible with conventional microstructured optical fibres, as well as the ability to functionalize the core of the fibre without interference from the cladding. The fabrication of such a fibre using PMMA is presented, as well as experimental results demonstrating the use of the fibre as a evanescent wave absorption spectroscopy pH sensor using the indicator Bromothymol Blue.
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