Observing chemical reactions in complex structures such as zeolites involves a major challenge in precisely capturing single-molecule behavior at ultra-high spatial resolutions. To address this, a sophisticated deep learning framework tailored has been developed for integrated Differential Phase Contrast Scanning Transmission Electron Microscopy (iDPC-STEM) imaging under low-dose conditions. The framework utilizes a denoising super-resolution model (Denoising Inference Variational Autoencoder Super-Resolution (DIVAESR)) to effectively mitigate shot noise and thereby obtain substantially clearer atomic-resolved iDPC-STEM images.
View Article and Find Full Text PDFSymmetry is a motif featured in almost all areas of science, and understanding the mechanism of symmetry breaking is challenging. Similar to mutations that disrupt symmetry in evolution, defects in materials offer insight into symmetry breaking. Here, we investigate symmetry in intragenerational mutations and symmetry breaking in transgenerational mutations in the evolutionary growth system of carbon nanotubes (CNTs).
View Article and Find Full Text PDFBackground: The gay affirmative practice (GAP) scale is an effective tool for evaluating the beliefs and behaviors of health care professionals toward gay and lesbian clients.
Aim: This study aimed to examine the reliability and validity of the GAP scale among Chinese nurses.
Methods: A quantitative cross-sectional study was conducted to evaluate the Chinese version of the GAP (C-GAP) scale after translation and cross-cultural adaptation and to examine its psychometric characteristics.
Both the physicochemical properties of catalytic material and the structure of loaded catalyst layer (CL) on gas diffusion electrode (GDE) are of crucial importance in determining the conversion efficiency and product selectivity of carbon dioxide reduction reaction (CORR). However, the highly reducing reaction condition of CORR will lead to the uncontrollable structural and compositional changes of catalysts, making it difficult to tailor surface properties and microstructure of the real active species for favored products. Herein, the interlayer microenvironment of copper-based layered double hydroxides (LDHs) is rationally tuned by a facile ink solvent engineering, which affects both the surface characters and microstructure of CL on GDE, leading to distinct catalytic activity and product selectivity.
View Article and Find Full Text PDFThe penetration rate (PR) of tunnel boring machines (TBMs) is often used to evaluate tunneling performance and predict construction period costs. However, most penetration rate (PR) prediction models are based on a single specific project, which leads to poor universality of the models.Furthermore, the value of the cutter head speed set for the prediction of the construction period in the survey and planning stages depends on manual experience and lacks theoretical guidance.
View Article and Find Full Text PDFThe repair of large bone defects due to trauma, disease, and infection can be exceptionally challenging in the elderly. Despite best clinical practice, bone regeneration within contemporary, surgically implanted synthetic scaffolds is often problematic, inconsistent, and insufficient where additional osteobiological support is required to restore bone. Emergent smart multifunctional biomaterials may drive important and dynamic cellular crosstalk that directly targets, signals, stimulates, and promotes an innate bone repair response following age-related biological decline and when in the presence of disease or infection.
View Article and Find Full Text PDFThe directional transformation of carbon dioxide (CO) with renewable hydrogen into specific carbon-heavy products (C) of high value presents a sustainable route for net-zero chemical manufacture. However, it is still challenging to simultaneously achieve high activity and selectivity due to the unbalanced CO hydrogenation and C-C coupling rates on complementary active sites in a bifunctional catalyst, thus causing unexpected secondary reaction. Here we report LaFeO perovskite-mediated directional tandem conversion of CO towards heavy aromatics with high CO conversion (> 60%), exceptional aromatics selectivity among hydrocarbons (> 85%), and no obvious deactivation for 1000 hours.
View Article and Find Full Text PDFObjectives: To evaluate the effects of Nd:YAG laser irradiation on the microstructures of dentin surfaces and the long-term bond strength of dentin under simulated pulpal pressure.
Materials And Methods: Under simulated pulp pressure, 30 freshly extracted caries-free third molars were cut into 2-mm-thick dentin samples and then divided into five groups: the control and laser groups (93.3 J/cm; 124.
The structural exploration of three-dimensional covalent organic frameworks (3D COFs) is of great significance to the development of COF materials. Different from structurally diverse MOFs, which have a variety of connectivity (3-24), now the valency of 3D COFs is limited to only 4, 6, and 8. Therefore, the exploration of organic building blocks with higher connectivity is a necessary path to broaden the scope of 3D COF structures.
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