Transmetalation in Surface-Confined Single-Layer Organometallic Networks with Alkynyl-Metal-Alkynyl Linkages.

Transmetalation represents an appealing strategy toward fabricating and tuning functional metal-organic polymers and frameworks for diverse applications. In particular, building two-dimensional metal-organic and organometallic networks affords versatile nanoarchitectures of potential interest for nanodevices and quantum technology. The controlled replacement of embedded metal centers holds promise for exploring versatile material varieties by serial modification and different functionalization.

Performance of a novel self-adhesive bulk-fill composite hybrid in endodontically treated maxillary premolars: analysis of fracture resistance and failure mode.

This study evaluated the fracture resistance of endodontically treated maxillary premolars restored with a new self-adhesive composite hybrid material (Surefil one [SO]) using different protocols. A total of 72 maxillary premolars were divided into 6 groups (n = 12). The control group included intact teeth, and the other 5 groups included teeth in which disto-occlusal cavities were prepared and endodontic treatment was performed.

Analogous electronic states in graphene and planer metallic quantum dots.

Graphene nanostructures offer wide range of applications due to their distinguished and tunable electronic properties. Recently, atomic and molecular graphene were modeled following simple free-electron scattering by periodic muffin tin potential leading to remarkable agreement with density functional theory. Here we extend the analogy of the -electronic structures and quantum effects between atomic graphene quantum dots (QDs) and homogeneous planer metallic counterparts of similar size and shape.

Unconventional Band Structure via Combined Molecular Orbital and Lattice Symmetries in a Surface-Confined Metallated Graphdiyne Sheet.

Graphyne (GY) and graphdiyne (GDY)-based monolayers represent the next generation 2D carbon-rich materials with tunable structures and properties surpassing those of graphene. However, the detection of band formation in atomically thin GY/GDY analogues has been challenging, as both long-range order and atomic precision have to be fulfilled in the system. The present work reports direct evidence of band formation in on-surface synthesized metallated Ag-GDY sheets with mesoscopic (≈1 µm) regularity.

Digital Apps to Improve Mobility in Adults with Neurological Conditions: A Health App-Focused Systematic Review.

The provision of mobility exercises through a smartphone application (app) for people undertaking neurological rehabilitation may improve mobility outcomes. However, it is difficult for clinicians and consumers to select high-quality, appropriate apps. This review aimed to identify (1) which mobile health (mHealth) apps are suitable for prescribing mobility exercises for adults with neurological health conditions, (2) how well these apps incorporate telehealth strategies, and (3) how well these apps rate in terms of quality and capacity for behaviour change.

Deceptive orbital confinement at edges and pores of carbon-based 1D and 2D nanoarchitectures.

The electronic structure defines the properties of graphene-based nanomaterials. Scanning tunneling microscopy/spectroscopy (STM/STS) experiments on graphene nanoribbons (GNRs), nanographenes, and nanoporous graphene (NPG) often determine an apparent electronic orbital confinement into the edges and nanopores, leading to dubious interpretations such as image potential states or super-atom molecular orbitals. We show that these measurements are subject to a wave function decay into the vacuum that masks the undisturbed electronic orbital shape.

Ultraconfined Plasmons in Atomically Thin Crystalline Silver Nanostructures.

The ability to confine light down to atomic scales is critical for the development of applications in optoelectronics and optical sensing as well as for the exploration of nanoscale quantum phenomena. Plasmons in metallic nanostructures with just a few atomic layers in thickness can achieve this type of confinement, although fabrication imperfections down to the subnanometer scale hinder actual developments. Here, narrow plasmons are demonstrated in atomically thin crystalline silver nanostructures fabricated by prepatterning silicon substrates and epitaxially depositing silver films of just a few atomic layers in thickness.

Formation of an Extended Quantum Dot Array Driven and Autoprotected by an Atom-Thick -BN Layer.

Engineering quantum phenomena of two-dimensional nearly free electron states has been at the forefront of nanoscience studies ever since the first creation of a quantum corral. Common strategies to fabricate confining nanoarchitectures rely on manipulation or on applying supramolecular chemistry principles. The resulting nanostructures do not protect the engineered electronic states against external influences, hampering the potential for future applications.

Efficient Removal of Mercury from Polluted Aqueous Solutions Using the Wireless Bipolar Electrochemistry Technique.

Mercury represents one of the major toxic pollutants in water that affect human and ecosystem. Extensive efforts have been globally invested to remove mercury using various chemical and electrochemical approaches. In this study, I propose the use of bipolar electrochemistry for the first time for mercury depollution process.

Nano-cellulose Reinforced Glass Ionomer Restorations: An In Vitro study.

Objective: Various modifications in formulation of glass ionomer cements (GICs) have been made in order to improve the clinical performance of these restorations. The aim of this work was to evaluate the microleakage and microshear bond strength (μSBS) of bacterial cellulose nanocrystal (BCNC)-modified glass ionomer cement (GIC) restorations in primary dentition.

Methods: A total number of 60 freshly extracted primary molar teeth were selected.

Stress, Sleep Quality, and Academic Performance among Dental Students in Shiraz, Iran.

Background: Quality of sleep and stress level can affect the health, capacity of learning, and academic performance of the students. This study aimed to investigate the association between stress and sleep quality with academic performance among undergraduate clinical dental students in Shiraz, Iran.

Methods: This cross-sectional study was conducted during the second semester of the academic year 2020-2021 among clinical dental students at Shiraz Dental School, Iran.

Engineering novel surface electronic states complex supramolecular tessellations.

Tailoring Shockley surface-state (SS) electrons utilizing complex interfacial supramolecular tessellations was explored by low-temperature scanning tunnelling microscopy and spectroscopy, combined with computational modelling using electron plane wave expansion (EPWE) and empirical tight-binding (TB) methods. Employing a recently introduced gas-mediated on-surface reaction protocol, three distinct types of open porous networks comprising paired organometallic species as basic tectons were selectively synthesized. In particular, these supramolecular networks feature semiregular Archimedean tilings, providing intricate quantum dots (QDs) coupling scenarios compared to hexagonal porous superlattices.

Effect of Tannic Acid and Quercetin Antioxidants on Bond Strength of Resin Cement to Dentin after Internal Bleaching.

Purpose: To evaluate the influence of tannic acid and quercetin on the immediate microshear bond strength (μSBS) of two resin cements to dentin after internal bleaching.

Materials And Methods: The access cavity in eighty extracted maxillary incisors was internally bleached except the control groups. The labial surfaces were ground to expose a flat dentin surface.

Atomically-Precise Texturing of Hexagonal Boron Nitride Nanostripes.

Monolayer hexagonal boron nitride (hBN) is attracting considerable attention because of its potential applications in areas such as nano- and opto-electronics, quantum optics and nanomagnetism. However, the implementation of such functional hBN demands precise lateral nanostructuration and integration with other two-dimensional materials, and hence, novel routes of synthesis beyond exfoliation. Here, a disruptive approach is demonstrated, namely, imprinting the lateral pattern of an atomically stepped one-dimensional template into a hBN monolayer.

Near Fermi Superatom State Stabilized by Surface State Resonances in a Multiporous Molecular Network.

Two-dimensional honeycomb molecular networks confine a substrate's surface electrons within their pores, providing an ideal playground to investigate the quantum electron scattering phenomena. Besides surface state confinement, laterally protruding organic states can collectively hybridize at the smallest pores into superatom molecular orbitals. Although both types of pore states could be simultaneously hosted within nanocavities, their coexistence and possible interaction are unexplored.

Microshear Bond Strength of Nanoparticle-Incorporated Conventional and Resin-Modified Glass Ionomer to Caries-Affected Dentin.

The purpose of this study was to assess the influence of three different types of nanoparticles (silver (SNPs), titanium dioxide (TNPs), and zinc oxide (ZNPs)) on the microshear bond strength of conventional glass ionomer cement (CGIC) and resin-modified glass ionomer cement based on whether CGIC or RMGIC is used with four subgroups (based on the incorporation of SNPs, ZNPs, and TNPs in addition to a control subgroup) ( = 12) as follows: CGIC, CGIC + TNP, CGIC + ZNP, CGIC + SNP, RMGIC, RMGIC + TNP, RMGIC + ZNP, and RMGIC + SNP. After 24 hours, the SBS of specimens was tested and the obtained data were analyzed using two-way ANOVA and Tukey's HSD test. The obtained results showed that the incorporation of TNPs in two glass ionomers was not statistically significant compared with the control subgroups ( > 0.

Metallic bands in chevron-type polyacenes.

We present electronic structure calculations based on a single-parameter plane wave expansion method for basic graphene building blocks, namely -oligophenylenes and -oligoacenes, revealing excellent agreement with density-functional theory. When oligophenylene molecules are joined through (zigzag) or (chevron) junctions, the resulting molecular dimers and polymers exhibit a semiconducting character. While zigzag dimers of oligoacenes also exhibit gapped electronic structures, their chevron-phase features a sharp metallic band at the Fermi energy.

The Effects of Silver, Zinc Oxide, and Titanium Dioxide Nanoparticles Used as Dentin Pretreatments on the Microshear Bond Strength of a Conventional Glass Ionomer Cement to Dentin.

Aim: This study was conducted to evaluate the effects of three nanoparticle solutions used as dentin pretreatments on the microshear bond strength (µSBS) of a conventional glass ionomer cement (GIC) to dentin.

Materials And Methods: Ninety intact human molars were used after sectioning their occlusal surfaces to expose flat dentin surfaces. The specimens were randomly assigned to nine groups (n = 10).

Electron Transmission through Coordinating Atoms Embedded in Metal-Organic Nanoporous Networks.

On-surface metal-organic nanoporous networks generally refer to adatom coordinated molecular arrays, which are characterized by the presence of well-defined and regular nanopores. These periodic structures constructed using two types of components confine the surface electrons of the substrate within their nanocavities. However, the confining (or scattering) strength that individual building units exhibit is a priori unknown.

Surface state tunable energy and mass renormalization from homothetic quantum dot arrays.

Quantum dot arrays in the form of molecular nanoporous networks are renowned for modifying the electronic surface properties through quantum confinement. Here we show that, compared to the pristine surface state, the band bottom of the confined states can exhibit downward shifts accompanied by a lowering of the effective masses simultaneous to the appearance of tiny gaps at the Brillouin zone boundaries. We observed these effects by angle resolved photoemission for two self-assembled homothetic (scalable) Co-coordinated metal-organic networks.

Effect of operator skill on the dentin bonding ability of a self-adhesive resin cement after different adhesive treatments.

This study evaluated the influence of operator skill on the shear bond strength of a self-adhesive resin cement to dentin after different adhesive treatments. Flat dentin surfaces were prepared on 160 extracted molars. The teeth were distributed evenly (n = 80) to 2 groups based on the operator's skill (undergraduate dental student vs operative dentistry specialist).

Controlling the stereospecific bonding motif of Au-thiolate links.

Over the last decades, organosulfur compounds at the interface of noble metals have proved to be extremely versatile systems for both fundamental and applied research. However, the anchoring of thiols to gold remained an object of controversy for a long time. The RS-Au-SR linkage, in particular, is a robust bonding configuration that displays interesting properties.

Plasmonics in Atomically Thin Crystalline Silver Films.

Light-matter interaction at the atomic scale rules fundamental phenomena such as photoemission and lasing while enabling basic everyday technologies, including photovoltaics and optical communications. In this context, plasmons, the collective electron oscillations in conducting materials, are important because they allow the manipulation of optical fields at the nanoscale. The advent of graphene and other two-dimensional crystals has pushed plasmons down to genuinely atomic dimensions, displaying appealing properties such as a large electrical tunability.

Pneumatosis Intestinalis and Intestinal Perforation in a Patient Receiving Tocilizumab.

In this article, we report a case of pneumatosis intestinalis associated with tocilizumab use. This is a unique case and may explain the increased rate of idiopathic bowel perforation among patients taking tocilizumab.