Fabrication of Graphene-Based TiO@CeO and CeO@TiO Core-Shell Heterostructures for Enhanced Photocatalytic Activity and Cytotoxicity.

Development of light-harvesting properties and inhibition of photogenerated charge carrier recombination are of paramount significance in the photocatalytic process. In the present work, we described the synthesis of core-shell heterostructures, which are composed of titanium oxide (TiO) and cerium oxide (CeO) deposited on a reduced graphene oxide (rGO) surface as a conductive substrate. Following the synthesis of ternary rGO-CeO@TiO and rGO-TiO@CeO nanostructures, their photocatalytic activity was investigated toward the degradation of rhodamine B dye as an organic pollutant under UV light irradiation.

Facile fabrication of ternary MWCNTs/ZnO/Chitosan nanocomposite for enhanced photocatalytic degradation of methylene blue and antibacterial activity.

Developing a cheap, stable and effective photocatalyst is necessary for remediation of persistent organic pollutants. To address this challenge, we proposed a unique interfacial engineering technique and proper bandgap matching strategy to synthesize MWCNTs/ZnO/Chitosan ternary nanocomposite for effective photocatalytic application. The features of the prepared samples were determined by FESEM, TEM, EDX, elemental mapping, AFM, FT-IR, XRD, UV-Vis spectroscopy and BET surface analysis.

Luminescent excited-state intramolecular proton-transfer dyes based on 4-functionalized 6,6'-dimethyl-3,3'-dihydroxy-2,2'-bipyridine (BP(OH)2-Rs); DFT simulation study.

The 4-functionalized 6,6'-dimethyl-3,3'-dihydroxy-2,2'-bipyridine dyes (BP(OH)-Rs) have exhibited dienol and diketo emissions. The optimum geometrical structures for ground, singlet and triplet excited states are computed by DFT/B3LYP/6-31++G that showed the planarity of BP(OH)-Rs structure. The emission spectra of the molecules are determined in the gas-phase at singlet and triplet excited states using CIS/6-31++G.