Publications by authors named "Fatemeh Mohseni-Shahri"

The present study developed a green metallochromic sensor that detects aluminium (Al(III)) ions in solution and solid state using anthocyanin extract from purple onion peels embedded in bacterial cellulose nanofibers (BCNFs). The CIE Lab colour parameters demonstrated that Al(III) binding causes a sensible change in colour. A variety of metal ions including K, Mn, Cu, Hg, Cr, Pb and Ni were used to challenge the sensor to determine its selectivity.

View Article and Find Full Text PDF

Copper(II)/polyimide-linked covalent organic frameworks under solvent-free and microwave-assisted conditions have been used in an efficient one-pot protocol for the preparation of 2,4,5-trisubstituted imidazoles via benzil, aromatic aldehydes and ammonium acetate. By applying solvent-free conditions and microwave irradiation, three-component condensation provides safe operations, low pollution, quick access to products, and an easy set-up. As a result of its reusability, the catalyst can also be reutilized for many runs without missing any activity.

View Article and Find Full Text PDF

An intelligent pH-sensing indicator containing Roselle ( L.) (RS) anthocyanin and curcumin (CR) was developed and characterized as on-package indicator tags to check the freshness of shrimp during the storage at 4°C. FE-SEM and FT-IR analysis showed that RS and CR were successfully immobilized in the gelatin-glycerol film-forming substrate.

View Article and Find Full Text PDF

The environment and our health are negatively impacted by heavy metal ions, like Cu(II). The present study developed a green and effective metallochromic sensor that detects copper (Cu(II)) ions in solution and solid state using anthocyanin extract from black eggplant peels embedded in bacterial cellulose nanofibers (BCNF). Cu(II) is quantitatively detected by the sensing method with detection limits between 10-400 ppm and 20-300 ppm in solution and solid state, respectively.

View Article and Find Full Text PDF

Seafood products as a source of vitamins, minerals, and polyunsaturated fatty acids represent an important component of the human diet. However, they are susceptible to spoilage even under appropriate storage conditions, making it indispensable to develop freshness indicators. In this study, we introduce a green user-friendly pH indicator film for the naked-eye monitoring of fish spoilage.

View Article and Find Full Text PDF

The liquid crystal (LC) detection platform has been fabricated for the detection of hypochlorite ions (ClO) in aquatic solutions. In this system, an imine consisting of the ligand ()-2-((4-(diethylamino)-2-hydroxybenzylidene)amino)-5-methoxybenzenesulfonic acid (MBA) was doped in 4-cyano-4'-pentyl biphenyl as a selecting LC for ClO. When immersing the platform in a solution containing ClO, hypochlorite appears to react with the imine bond in the MBA, and cause it to cleave, which eventually disrupts the direction of LC and causes a dark-to-bright conversion of the LC image.

View Article and Find Full Text PDF

Quinoline yellow (QY) is one of the popular synthetic food colorants and in food industry greatly used. Developing accurate and simple QY detection procedures is of major considerable importance in ensuring food safety. Hence, it is important to detect this food colorant effectively to reduce risk.

View Article and Find Full Text PDF

In this study, a Schiff base derived from a heterocyclic moiety was synthesized and characterized. The in vitro binding behaviour of this ligand with β-casein (β-CN) was investigated using biophysical techniques. For evaluation, thermodynamics variables of interactions between the Schiff base ligand and β-CN, such as fluorescence at different temperatures, were measured.

View Article and Find Full Text PDF

In this study, two metal Schiff base complexes (cobalt(II) and manganese(II), were synthesized and characterized by H-NMR and FT-IR analyses. The in vitro binding behavior of this complexes with β-Casein (β-CN) was investigated by using biophysical techniques. For evaluation the thermodynamics parameters of interaction between Schiff base complexes and β-CN,the fluorescence data at different temperatures were done.

View Article and Find Full Text PDF

The interaction of pepsin with sunset yellow food additive (SY) was studied by fluorescence spectroscopy and molecular dynamics simulation. The experimental results indicated that SY can quench the fluorescence of pepsin with static quenching. The apparent binding constant K and binding site number n were evaluated at different temperatures.

View Article and Find Full Text PDF

β-Lactoglobulin (β-LG), the major whey protein in milks of many mammals, has a high affinity for a wide range of compounds. Cyclosporine A (CsA), is an immunosuppressant drug mainly prescribe in organ transplantation to prevent rejection. In this study, the interaction of CsA with β-LG was investigated using various spectroscopic techniques (UV-visible and fluorescence) in an aqueous medium at two temperatures of 298 and 310K in combination with a molecular dynamics simulation study.

View Article and Find Full Text PDF

The interaction between losartan and human serum albumin (HSA), as well as its glycated form (gHSA) was studied by multiple spectroscopic techniques and molecular dynamics simulation under physiological conditions. The binding information, including the binding constants, effective quenching constant and number of binding sites showed that the binding partiality of losartan to HSA was higher than to gHSA. The findings of three-dimensional fluorescence spectra demonstrated that the binding of losartan to HSA and gHSA would alter the protein conformation.

View Article and Find Full Text PDF