Fabrication of ternary NiCoMoO with yolk-shell hollow structure as a positive electrode material for high-performance electrochemical capacitor applications.

Although the fabrication of hollow nanostructures from single and binary transition metal oxides has been accomplished effectively, there still exists a significant challenge in creating advanced hollow morphologies comprising mixed transition metal oxides such as ternary and quaternary compositions. In this context, we have adopted an alternative approach by employing a straightforward self-templating method to synthesize ternary metal molybdate nanomaterials. These materials possess the chemical composition of NiCoMoO and exhibit a unique nanoporous yolk-shell hollow structure.

Natural sensitizer extracted from Mussaenda erythrophylla for dye-sensitized solar cell.

In this study, a natural dye from the flowers of Mussaenda erythrophylla extracted separately in ethanol and de-ionized water was employed as a photosensitizer in DSSCs. The quantitative phytochemical analyses were performed on both extracts. The existence of flavonoids (anthocyanin) and chlorophyll a pigments in the ethanol extract of the dye was confirmed by the UV-Visible spectroscopy.

Hierarchical Cube-in-Cube Cobalt-Molybdenum Phosphide Hollow Nanoboxes Derived from the MOF Template Strategy for High-Performance Supercapacitors.

The design of hierarchical hollow nanostructures with complex shell architectures is an attractive and effective way to obtain a desirable electrode material for energy storage application. Herein, we report an effective metal-organic framework (MOF) template-engaged method to synthesize novel double-shelled hollow nanoboxes, in terms of chemical composition and structure complexity, for supercapacitor application. Starting from cobalt-based zeolitic imidazolate framework (ZIF-67(Co)) nanoboxes as the removal template, we developed a rational preparation approach to synthesize cobalt-molybdenum-phosphide (CoMoP) double-shelled hollow nanoboxes (donated as CoMoP-DSHNBs) through (i) ion-exchange reaction, (ii) template etching, and (iii) phosphorization treatment, respectively.

Air processed CsAgBiBr lead-free double perovskite high-mobility thin-film field-effect transistors.

This study focuses on the fabrication and characterization of CsAgBiBr double perovskite thin film for field-effect transistor (FET) applications. The CsAgBiBr thin films were fabricated using a solution process technique and the observed XRD patterns demonstrate no diffraction peaks of secondary phases, which confirm the phase-pure crystalline nature. The average grain sizes of the spin-deposited film were also calculated by analysing the statistics of grain size in the SEM image and was found to be around 412 (± 44) nm, and larger grain size was also confirmed by the XRD measurements.

A Review on Cs-Based Pb-Free Double Halide Perovskites: From Theoretical and Experimental Studies to Doping and Applications.

Despite the progressive enhancement in the flexibility of Pb-based perovskites for optoelectronic applications, regrettably, they are facing two main challenges; (1) instability, which originates from using organic components in the perovskite structure, and (2) toxicity due to Pb. Therefore, new, stable non-toxic perovskite materials are demanded to overcome these drawbacks. The research community has been working on a wide variety of Pb-free perovskites with different molecular formulas and dimensionality.