The support effect on the performance of a MOF-derived Co-based nano-catalyst in Fischer Tropsch synthesis.

The catalyst plays a central role in the Fischer-Tropsch synthesis (FTS) process, and the choice of catalyst support significantly impacts FTS catalyst performance by enhancing its attributes. In this study, the effects of utilizing various metal oxides-CeO, ZrO, and TiO-on a cobalt-based FTS nanocatalyst are investigated by evaluating the catalyst's reducibility, stability, syngas chemisorption, intermediate species spillover, charge transfer, and metal-support interaction (MSI). This evaluation is conducted both theoretically and experimentally through diverse characterization tests and molecular dynamics (MD) simulations.