Nonzero spontaneous electric polarization in metals: novel predictive methods and applications.

Ferroelectricity in metals has advanced since the initial discovery of nonmagnetic ferroelectric-like metal LiOsO[Formula: see text], anchored in the Anderson and Blount prediction. However, evaluating the spontaneous electric polarization (SEP) of this metal has been hindered by experimental and theoretical obstacles. The experimental challenge arises from difficulties in switching polarization using an external electric field, while the theoretical limitation lies in existing methods applicable only to nonmetals.