Prussian blue analogues, as prospective electrode materials, play a crucial role in detecting heavy metal ions (HMIs), a process closely related to their electron transfer capacities and active surfaces. Here, etched copper-iron Prussian blue analogues (CuFe-PBA) are synthesized through a combination of flash nanoprecipitation (FNP) and an alkali etching process. Furthermore, this study investigates the impact of ammonia on the electronic structure of CuFe-PBA and its electrochemical detection capabilities for HMIs.
View Article and Find Full Text PDFA stable ratiometric electrochemical sensing platform is introduced for the determination of p-phenylenediamine (PPD). Specifically, the proposed sensing platform employs nitrogen-doped MOF pyrolysis-derived CoNi/C (N-CoNi/C) which was deployed as the sensing agent and methylene blue (MB) as the internal reference, and the MB combined with N-CoNi/C nanomaterials by a simple immersion adsorption process. Full characterization of N-CoNi/C was carried out with respect to morphology, composition, and electrochemical behavior, and the sensing performance of the ratiometric electrochemical sensing platform was evaluated.
View Article and Find Full Text PDFAs a β-stimulant, clenbuterol (CLB) is abused to varying degrees by athletes worldwide. It is also used in the meat and dairy industries. CLB inadvertently enters the human body through the food chain, endangering human health.
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