For sustained hydrogen generation from seawater electrolysis, an efficient and specialized catalyst must be designed to cope with the slow anode reaction and chloride ions (Cl) corrosion. In this work, an S-modified NiFe-phosphate with hierarchical and hollow microspheres was grown on the NiFe foam skeleton (S-NiFe-Pi/NFF), acting as a bifunctional catalyst to enable industrial-scale seawater electrolysis. The introduction of S distorted the lattice of NiFe-phosphate and regulated the local electronic environment around Ni/Fe active metal, both of which enhanced the electrocatalytic activity.
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