The laser-plasma interactions that occur during the ablation of solid materials by a femtosecond filament superimposed with a lower-intensity nanosecond pulse are investigated. Pulses of 50 fs duration with intensities of ∼10 W/cm centered at 800 nm are combined with 8 ns pulses at 1064 nm with ∼10 W/cm intensity with delays of ±40 ns on crystalline GaAs targets in air. For each delay, the volume of material removed by a single femtosecond-nanosecond dual-pulse is compared to the laser-plasma interactions that are captured with ultrafast shadowgraph imaging of the plasma and shockwave generated by each pulse.
View Article and Find Full Text PDFIn sentences such as "Some dogs are mammals," the literal semantic meaning ("Some and possibly all dogs are mammals") conflicts with the pragmatic meaning ("Not all dogs are mammals," known as a scalar implicature). Prior work has shown that adults vary widely in the extent to which they adopt the semantic or pragmatic meaning of such utterances, yet the underlying reason for this variation is unknown. Drawing on theoretical models of scalar implicature derivation, we explore the hypothesis that the cognitive abilities of executive function (EF) and theory of mind (ToM) contribute to this observed variation.
View Article and Find Full Text PDFLaser filament applications relying on filament plasma conductivity are limited by their low electron densities and corresponding short lifetimes. Filament plasma formation, an intensity-dependent process, is limited by the clamping of the filament core intensity. Consequently, increasing initial beam energy results in the breakup of the beam into multiple filaments rather than the enhancement of the electron density and conductivity of an individual filament.
View Article and Find Full Text PDFForeign-accented non-native speakers sometimes face negative biases compared to native speakers. Here we report an advantage in how comprehenders process the speech of non-native compared to native speakers. In a series of four experiments, we find that under-informative sentences are interpreted differently when attributed to non-native compared to native speakers.
View Article and Find Full Text PDFWavefront measurements are used to characterize the process of filament formation in air under assisted-collapse conditions. Direct wavefront evolution within the filament, measured for the first time, is used to characterize the role of energy reservoir in filament formation. This information provides new insights into the filament process and phase sensitive applications such as engineered plasma waveguides.
View Article and Find Full Text PDFLaser filaments can project intensities sufficient to ablate materials at long ranges, but the clamping of a filament's intensity to ∼10 W/cm limits the effective ablation of targets with which the laser pulses interact. We seek to identify regimes in which auxiliary radiation can be used to augment the ablation created by single filaments. In this work, the combination of an 800 nm, 50 fs beam at single filament intensity and a 1064 nm, 8 ns laser pulse is studied.
View Article and Find Full Text PDFThe propagation distance of a pulsed beam in free space is ultimately limited by diffraction and space-time coupling. "Space-time" (ST) wave packets are pulsed beams endowed with tight spatio-temporal spectral correlations that render them propagation-invariant. Here we explore the limits of the propagation distance for ST wave packets.
View Article and Find Full Text PDFUtterances produced by foreign-accented speakers are often judged as less credible, more vague, and more difficult to understand compared to those produced by native speakers. Some theoretical accounts argue that listeners have different expectations about the speech of non-native speakers. Other accounts argue that non-native speech is processed differently to the extent that a foreign accent taxes intelligibility and introduces additional processing load.
View Article and Find Full Text PDFSpace-time wave packets are a class of pulsed optical beams that are diffraction-free and dispersion-free in free space by virtue of introducing a tight correlation between the spatial and temporal degrees of freedom of the field. Such wave packets have been recently synthesized in a novel configuration that makes use of a spatial light modulator to realize the required spatio-temporal correlations. This arrangement combines pulse-modulation and beam-shaping to assign one spatial frequency to each wavelength according to a prescribed correlation function.
View Article and Find Full Text PDFObjectives: Integrative medicine (IM) is whole-person care utilizing complementary health approaches to address numerous physical or emotional influences that can impact an individual's health. Patient-reported outcomes (PRO) are subjective measures that quantify patients' perception of their quality of life. While PRO measures have been routinely assessed in specific oncology clinics, our objective was to assess the ability and utility of routine collection of PRO measures in an IM clinic.
View Article and Find Full Text PDFWith its low work function and high mechanical strength, the LaB/VB eutectic system is an interesting candidate for high performance thermionic emitters. For the development of device applications, it is important to understand the origin, value, and spatial distribution of the work function in this system. Here we combine thermal emission electron microscopy and low energy electron microscopy with Auger electron spectroscopy and physical vapor deposition of the constituent elements to explore physical and chemical conditions governing the work function of these surfaces.
View Article and Find Full Text PDFDuring communication, hearers try to infer the speaker's intentions to be able to understand what the speaker means. Nevertheless, whether (and how early) preschoolers track their interlocutors' mental states is still a matter of debate. Furthermore, there is disagreement about how children's ability to consult a speaker's belief in communicative contexts relates to their ability to track someone's belief in non-communicative contexts.
View Article and Find Full Text PDFHeterostructures consisting of two-dimensional materials have shown new physical phenomena, novel electronic and optical properties, and new device concepts not observed in bulk material systems or purely three dimensional heterostructures. These new effects originated mostly from the van der Waals interaction between the different layers. Here we report that a new optical and electronic device platform can be provided by heterostructures of 2D graphene with a metal oxide (TiO2).
View Article and Find Full Text PDFAcid spun carbon nanotube (CNT) fibers were investigated for their field emission properties and performance was determined to be dependent on fiber morphology. The fibers were fabricated by wet-spinning of pre-made CNTs. Fiber morphology was controlled by a fabrication method and processing conditions, as well as purity, size, and type of the CNT starting material.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2013
Thin films of transition-metal carbides ZrC, HfC, and TiC were deposited by pulsed-laser deposition under vacuum. The surface chemistry of the films was characterized with ultraviolet photoelectron spectroscopy, X-ray photoelectron spectroscopy, and Auger electron spectroscopy in situ. X-ray diffraction was used to characterize the film structure.
View Article and Find Full Text PDFAn integral part of NICHE (Nurses Improving Care for Healthsystem Elders) is a benchmarking service that provides member sites with the ability to evaluate staff perceptions of the care environment compared with other NICHE sites. The NICHE Database includes more than 100,000 surveys (Geriatric Institutional Assessment Profile). This study aimed to explain how secondary analyses of this aggregate database can inform effective geriatric programming in hospitals.
View Article and Find Full Text PDFBroader applications of carbon nanotubes to real-world problems have largely gone unfulfilled because of difficult material synthesis and laborious processing. We report high-performance multifunctional carbon nanotube (CNT) fibers that combine the specific strength, stiffness, and thermal conductivity of carbon fibers with the specific electrical conductivity of metals. These fibers consist of bulk-grown CNTs and are produced by high-throughput wet spinning, the same process used to produce high-performance industrial fibers.
View Article and Find Full Text PDFHuman Serum paraoxonase 1 (HuPON1) is an enzyme that has been shown to hydrolyze a variety of chemicals including the nerve agent VX. While wildtype HuPON1 does not exhibit sufficient activity against VX to be used as an in vivo countermeasure, it has been suggested that increasing HuPON1's organophosphorous hydrolase activity by one or two orders of magnitude would make the enzyme suitable for this purpose. The binding interaction between HuPON1 and VX has recently been modeled, but the mechanism for VX hydrolysis is still unknown.
View Article and Find Full Text PDFHuman serum paraoxonase 1 (HuPON1) is an enzyme that can hydrolyze various chemical warfare nerve agents including VX. A previous study has suggested that increasing HuPON1's VX hydrolysis activity one to two orders of magnitude would make the enzyme an effective countermeasure for in vivo use against VX. This study helps facilitate further engineering of HuPON1 for enhanced VX-hydrolase activity by computationally characterizing HuPON1's tertiary structure and how HuPON1 binds VX.
View Article and Find Full Text PDFBackground: Quality improvement (QI) is a focus of hospital managers and policymakers. The role of registered nurses (RNs) in QI in hospitals is vital because most hospital-based RNs provide direct care to patients. QI skills are necessary to identify gaps between current care and best practice and to design, implement, test, and evaluate changes and are essential for R.
View Article and Find Full Text PDFThe Geriatric Institutional Assessment Profile (GIAP) is a self-administered survey of hospital nurses, designed to assess a hospital's readiness to implement geriatric programs. A sample of 2,211 direct care RNs in 24 hospitals was randomly split in half to analyze the Geriatric Professional Issues scales of the GIAP, using one sample for exploratory factor analysis and one for confirmatory factor analysis. An exploratory factor analysis of the six Geriatric Professional Issue scales (staff disagreement, staff/family/patient disagreement, use of geriatric services, perceived legal vulnerability, perceived upsetting behaviors, and burden of upsetting behaviors) demonstrated very good internal consistency both as a whole (Cronbach's alpha coefficient = 0.
View Article and Find Full Text PDFAccurately computing molecular Raman spectra would enable rapid development of inexpensive and extensive Raman libraries. This is especially beneficial for chemicals that are regulated, toxic, or otherwise difficult to handle. Numerous quantum mechanical methods have been developed that enable computation of Raman spectra.
View Article and Find Full Text PDFNursing turnover is costly for health care organizations. Newly licensed registered nurses work behavior is a complex process, influenced by their attitudes toward their work, personal characteristics, job opportunities, and workplace attributes. Several characteristics are significant in predicting satisfaction (ethnicity, gender) and organizational commitment (patient load, mandatory overtime, shift, and unit type) and intent to stay (income, age) over and above work attitudes.
View Article and Find Full Text PDFThe Geriatric Institutional Assessment Profile (GIAP) is a self-administered survey of hospital nurses designed to assess a hospital's readiness to implement geriatric programs. The GIAP measures nurses' knowledge and attitudes toward older adults as well as the organizational attributes that support or constrain geriatric best practices. Test-retest reliability estimates of the GIAP were conducted with a sample of 166 direct care nurses in three urban, university-affiliated hospitals over a 3-week time period.
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