The dry reforming of methane (DRM) was studied for seven hours at 800 °C and 42 L/(g·h) gas hourly space velocity over Ni-based catalysts, promoted with various amounts of gadolinium oxide (x = 0.0, 1.0, 2.
View Article and Find Full Text PDFThe carbon dioxide reforming of methane has attracted attention from researchers owing to its possibility of both mitigating the hazards of reactants and producing useful chemical intermediates. In this framework, the activity of the nickel-based catalysts, supported by yttria-stabilized zirconia and promoted with holmium oxide (HoO), was assessed in carbon dioxide reforming of methane at 800 °C. The catalysts were characterized by N-physisorption, H temperature-programmed reduction, temperature-programmed desorption of CO, X-ray diffraction, scanning electron microscopy (SEM) together with energy-dispersive X-ray spectroscopy, transmission electron microscopy (TEM), and thermogravimetric analysis (TGA) techniques.
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