Publications by authors named "Fabio Iucolano"

The preservation of cultural heritage, particularly historical stone structures, represents a very challenging matter due to several environmental and anthropogenic factors. Vicenza stone, a calcareous rock known for its historical significance and widespread use in architectural masterpieces, requires significant attention for conservation. In fact, as the demand for sustainable and effective preservation methods intensifies, the exploration of innovative consolidation strategies becomes essential.

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This research explores the new perspectives in conservation and protection of two macroporous tuff stones, widely employed in the architectural heritage of Campania region, characterized by highly heterogeneous rock fabric and texture and a variable mineralogical composition that represent crucial factors responsible for their weak durability. The consolidation treatments were performed with a recently and widely used suspension of nano-silica crystals in water and with a lithium silicate solution that has received up to now scarce attention as a consolidant agent. Physical investigations (open porosity, Hg porosimetry, water absorption), morphological observations (SEM analyses) and visual appearance test (colorimetric measurements), along with assessments of performance indicators such as ultrasonic pulse velocity, surface cohesion test (peeling test) and durability test (salt crystallization), were carried out to investigate the consolidation effectiveness.

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A great challenge of research is the utilization of natural or synthetic zeolites, in place of natural pozzolans, for manufacturing blended cements. The difficulties of interpretation of the pozzolanic behavior of natural zeolite-rich materials and the role played by their nature and composition can be overcome by studying more simple systems, such as pure synthetic zeolites. This study aims at investigating the pozzolanic ability of isostructural zeolites with different framework compositions, such as three sodium zeolites of the faujasite (FAU) framework type: LSX, X, and Y.

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Sustainable building material design relies mostly on energy saving processes, decrease of raw materials consumption, and increase of waste and by-products recycling. Natural and lightweight artificial aggregates production implies relevant environmental impact. This paper addresses both the issues of residues recycling and energy optimization.

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The effect of pH changes on the ability of the synthetic zeolite NaA to remove Cr(3+) from water by ion exchange was investigated. The exchange rate was improved by working near neutrality. Despite of the occurrence of simultaneous adsorption, precipitation or cation exchange phenomena, spectroscopic analyses of samples taken at different contact times suggested the presence of an unique chromium environment in the solid phase.

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