Manipulating electron transfer - the influence of substituents on novel copper guanidine quinolinyl complexes.

Copper guanidine quinolinyl complexes act as good entatic state models due to their distorted structures leading to a high similarity between Cu(i) and Cu(ii) complexes. For a better understanding of the entatic state principle regarding electron transfer a series of guanidine quinolinyl ligands with different substituents in the 2- and 4-position were synthesized to examine the influence on the electron transfer properties of the corresponding copper complexes. Substituents with different steric or electronic influences were chosen.