Recent advancements in activated carbon production involve molten salt activation using a eutectic mixture of ZnCl-NaCl-KCl. This study explores the production of activated carbon from fruit waste, specifically walnut shells, using a 60:20:20 mol % eutectic mixture. Optimal conditions were identified through response surface methodology, with 400 °C and a salt-to-biomass ratio of 10 g/g, yielding a surface area of 276 m/g.
View Article and Find Full Text PDFThe production of aviation biofuel precursors from biomass-derived ketones by heterogeneous catalysis has been hindered by the low catalytic activity. Herein, a series of Cu-doped metal oxide catalysts were prepared for the conversion of biomass-derived ketones to aviation biofuel precursors. Solvent-free cyclopentanone conversion via aldol condensation reached 91.
View Article and Find Full Text PDFThis study assessed the hydrochar production potential of fish and crustacean waste from 8 marine species (Scomber japonicus, Trichiurus lepturus, Larimichthys polyactis, Trachurus trachurus, Paralichthys olivaceus Litopenaeus vannamei, Portunus trituberculatus, and Penaeus monodon) through hydrothermal carbonization (HTC) of their waste fractions. The impact of reaction temperature (200 - 240°C), fixed residence time (5 h), and water-to-biomass ratio (7) on HTC was analyzed. The results showed that hydrochar yields varied between fish (15.
View Article and Find Full Text PDFDue to the natural biochar aging, the improvement of soil quality and immobilization of soil pollutants achieved by biochar may change; understanding the dynamic evolution of the in situ performance of biochar in these roles is essential to discuss the long-term sustainability of biochar remediation. Therefore, in this study, combined biochar from co-pyrolysis of pig manure and invasive Japanese knotweed - P1J1, as well as pure pig manure - PM - and pure Japanese knotweed - JK - derived biochar were applied to investigate their remediation performance in a high As- and Pb-polluted soil with prolonged incubation periods (up to 360 days). Biochar application, especially P1J1 and PM, initially promoted soil pH, dissolved organic carbon, and EC, but the improvements were not constant through time.
View Article and Find Full Text PDFThe remediation performance of biochar varies based on the biomass used for its production. Further innovation involves developing tailor-made biochar by combining different raw materials to compensate for the limitations of pure biochar. Therefore, tailor-made combined biochar produced from the co-pyrolysis of pig manure and invasive Japanese knotweed (P1J1), as well as biochars produced from these feedstocks separately, i.
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