Publications by authors named "F J Silvestre Donat"

Smart packaging technologies are revolutionizing the food industry by extending shelf life and enhancing quality monitoring through environmental responsiveness. Here, a novel smart packaging concept is presented, based on amyloid fibrils (AM) and red radish anthocyanins (RRA), to effectively monitor food spoilage by color change. A protein nanofibrils biofilm is developed from whey protein, which is functionalized with RRA to endow the resulting films with advanced monitoring capabilities.

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Chemical looping (CL) has emerged as a promising approach in the oxidative dehydrogenation (ODH) of light alkanes, offering an opportunity for significant reductions in emissions and energy consumption in the ethylene and propylene production industry. While high olefin yields are achievable via CL, the material requirements (e.g.

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Chemical looping air separation (CLAS) is a promising process intensification technology for extracting oxygen from air for oxygen enrichment in process streams. Co-doped strontium ferrites (SrFeCoO) have been found to have outstanding activities for CLAS processes. In this study, we explore the underlying factors driving the enhancement in oxygen uptake and release performance of perovskite structured SrFeCoO oxygen carriers for CLAS.

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Constructing effective antidotes to reduce global health impacts induced by alcohol prevalence is a challenging topic. Despite the positive effects observed with intravenous applications of natural enzyme complexes, their insufficient activities and complicated usage often result in the accumulation of toxic acetaldehyde, which raises important clinical concerns, highlighting the pressing need for stable oral strategies. Here we present an effective solution for alcohol detoxification by employing a biomimetic-nanozyme amyloid hydrogel as an orally administered catalytic platform.

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Monitoring the spontaneous reconstruction of the surface of metal oxides under electrocatalytic reaction conditions is critical to identifying the active sites and establishing structure-activity relationships. Here, we report on a self-terminated surface reconstruction of Ruddlesden-Popper lanthanum nickel oxide (LaNiO) that occurs spontaneously during reaction with alkaline electrolyte species. Using a combination of high-resolution scanning transmission electron microscopy (HR-STEM), surface-sensitive X-ray photoelectron spectroscopy (XPS), and soft X-ray absorption spectroscopy (sXAS), as well as electrochemical techniques, we identify the structure of the reconstructed surface layer as an amorphous (oxy)hydroxide phase that features abundant under-coordinated nickel sites.

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