Most of our energy consumption proceeds from the use of fossil fuels and the production of natural gas. However, the presence of impurities in this gas, like CO, makes treatment necessary to avoid further concerns, such as greenhouse gas emissions, the corrosion of industrial equipment, etc.; thus, the development of CO capture and storage procedures is of the utmost importance in order to decrease CO production and mitigate its contribution to global warming.
View Article and Find Full Text PDFThe presence of organic dyes in aqueous environments is extremely hazardous to life due to the toxicity of these compounds. Thus, its removal from these various aquatic media is of the utmost importance, and several technologies are constantly being tested to meet this goal. Among these technologies, various types of degradation and adsorption techniques are typically used, and of the various types of materials used within these technologies, nanomaterials are constantly being developed and investigated, likely due to the various properties that these nanomaterials have.
View Article and Find Full Text PDFThe removal of chromium(VI) from an acidic (HCl) medium through non-dispersive extraction with strip dispersion (NDXSD) was investigated using a microporous PVDF membrane support in a permeation cell. The ionic liquid Cyphos IL102 (phosphonium salt) in Solvesso 100 was used as an organic phase. In NDXSD, the stripping phase (NaOH) is dispersed in the organic phase on the cell side with an impeller stirrer adequate to form a strip dispersion.
View Article and Find Full Text PDFThe boosted interest in using rare earth elements (REEs) in modern technologies has also increased the necessity of their recovery from various sources, including raw materials and wastes. Though hydrometallurgy plays a key role in these recovery processes, some drawbacks (apparent or not) of these processes (including the use of aggressive mineral acids, harmful extractants, and diluents, etc.) have led to the development of an environmental friendship subclass named solvometallurgy, in which non-aqueous solvents substituted to the aqueous media of the hydrometallurgical processing.
View Article and Find Full Text PDFThe removal of harmful arsenic(V) from aqueous solutions using Cyanex 923 (solvation extractant) was investigated using various experimental variables: equilibration time, the acidity of the aqueous phase, temperature, extractant and arsenic concentrations, and O/A ratio. Cyanex 923 extracted As(V) (and sulfuric acid) from acidic solutions; however, it could not be used to remove the metal from slightly acid or neutral solutions. The extraction of arsenic is exothermic and responded to the formation of HAsO·nL species in the organic phase (L represents the extractant, and the stoichiometric factor, n = 1 or 2, depends on the acidity of the aqueous phase).
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