Composition and sources of sediment organic matter in a western Iberian salt marsh: Developing a novel prediction model of the bromine sedimentary pool.

Salt marshes are sensitive highly productive habitats crucial for carbon cycling. This study presents a comprehensive analysis of organic geochemical indicators and geochronology in the Mira salt marsh (SW Portugal) over eight centuries. The closely intertwined carbon and bromine (Br) biogeochemical cycles in these environments can influence the fluxes of volatile compounds such as ozone-depleting methyl bromide, emphasizing the importance of understanding sediment organic matter (OM) origin, budget, and composition in salt marshes.

Bromine biogeodynamics in the NE Atlantic: A perspective from natural wetlands of western Portugal.

Bromine (Br) cycling in natural wetlands is highly complex, including abiotic/biotic processes and multiphase inorganic/organic Br-species. Wetland ecosystems receive Br primarily from the ocean, functioning as either sinks or sources of Br, with the overall imbalance largely decided by the prevailing climate. Aiming to trace the present-day transport of oceanogenic Br (i.

Refractory organic matter in coastal salt marshes-effect on C sequestration calculations.

The age and ability of salt marshes to accumulate and sequester carbon is often assessed using the carbon isotopic signatures (ΔC and δC) of sedimentary organic matter. However, transfers of allochthonous refractory carbon (C) from the watershed to marshes would not represent new C sequestration. To better understand how refractory carbon (C) inputs affect assessments of marsh age and C sequestration, ΔC and δC of both total organic carbon (TOC), C, and non-C organic matter fractions were measured in salt marshes from four contrasting systems on the North Atlantic coast.

Bromine soil/sediment enrichment in tidal salt marshes as a potential indicator of climate changes driven by solar activity: New insights from W coast Portuguese estuaries.

This paper aims at providing insight about bromine (Br) cycle in four Portuguese estuaries: Minho, Lima (in the NW coast) and Sado, Mira (in the SW coast). The focus is on their tidal marsh environments, quite distinct with regard to key biophysicochemical attributes. Regardless of the primary bromide (Br) common natural source, i.

Bromine enrichment in marsh sediments as a marker of environmental changes driven by Grand Solar Minima and anthropogenic activity (Caminha, NW of Portugal).

A sediment core collected in Caminha tidal marsh, NW Portugal, was used to assess bromine (Br) signal over the last ca. 1,700 years. The Br temporal variability reflects its close relationship with soil/sediment organic matter (OM) and also alterations in Br biogeochemical recycling in marsh environment.