A novel electrochemical sensor for the determination of cadmium ions based on nitrogen-enriched carbon modified electrode.

In the present work, nitrogen-doped carbon was synthesized starting from a chitosan/urea mixture and immobilized at the surface of a bare glassy carbon electrode to detect Cd(II) ions using differential pulse-anodic stripping voltammetry method (DP-ASV). The synthesized nitrogen-doped carbon showed a significant potential for determining Cd(II) ions. Doping carbon with nitrogen atoms gives a structure with increased valence band energy, leading to acceleration of the electron transfer by creating an interaction of nitrogen's free electrons with Cd(II), which subsequently increases the peak current value.

Development of isoniazid electrochemical sensor using nickel ferrite - nitrogen and sulfur co-doped graphene quantum dot nanocomposite as a new electrode modifier.

This work reports the synthesis of nickel ferrite decorated nitrogen and sulfur co-doped graphene quantum dot (NF@N, S:GQD) and its use as an electrode modifier. The developed NF@N, S:GQD modified glassy carbon electrode (NF@N, S:GQD/GCE) was applied to assess isoniazid (INZ) concentration based on its oxidation at the surface of the proposed electrode. Cyclic voltammetry (CV) and differential pulse voltammetry (DPV) were used as appropriate electrochemical techniques to study the electrochemical behavior of INZ and determine it.

Electrochemical determination of ascorbic acid using palladium supported on N-doped graphene quantum dot modified electrode.

To precise screening concentration of ascorbic acid (AA), a novel electrochemical sensor was prepared using palladium nanoparticles decorated on nitrogen-doped graphene quantum dot modified glassy carbon electrode (PdNPs@N-GQD/GCE). For this purpose, nitrogen doped GQD nanoparticles (N-GQD) were synthesized from a citric acid condensation reaction in the presence of ethylenediamine and subsequently modified by palladium nanoparticles (PdNPs). The electrochemical behavior of AA was investigated, in which the oxidation peak appeared at 0 V related to the AA oxidation.

An electrochemical sensor for the detection of arsenic using nanocomposite-modified electrode.

The aim of this research is to develop an electrochemical sensor based on a conducting polymer, polyaniline, and a cationic polymer, poly(diallyldimethylammonium chloride), reinforced with graphene oxide nanosheets functionalized with acrylic acid. The two-dimensional nature of acrylic acid functionalized graphene oxide nanosheets and clusters made of conductive polymers and acrylic acid functionalized graphene oxide nanosheets were confirmed by microscopic tests. The prepared nanocomposite was deposited on the glassy carbon electrode in order to prepare an electrochemical sensor for the detection of arsenic by cyclic voltammetry and differential pulse voltammetry methods.

Determination of trace amount of iron cations using electrochemical methods at N, S doped GQD modified electrode.

In this work, nitrogen and sulfur co-doped graphene quantum dot-modified glassy carbon electrodes (N, S-GQD/GCE) were used for the recognition of iron cations in aqueous solutions. The dissolved cations are detected based on the faradaic reduction or oxidation current of Fe(III) and Fe(II) obtained at the N, S-GQD/GCE surface. Cyclic voltammetry (CV), square wave voltammetry (SWV), and hydrodynamic amperometry are used as suitable electrochemical techniques for studying electrochemical behavior and determination of Fe cations.