Multiresonant all-dielectric metasurfaces based on high-order multipole coupling in the visible.

In many cases, optical metasurfaces are studied in the single-resonant regime. However, a multiresonant behavior can enable multiband devices with reduced footprint, and is desired for applications such as display pixels, multispectral imaging and sensing. Multiresonances are typically achieved by engineering the array lattice (e.

Low-frequency magnetic response of gold nanoparticles.

Gold nanoparticles (AuNPs) exposed to low frequency magnetic fields have shown promise in enhancing biological processes, such as cellular reprogramming. Despite the experimental evidence, a comprehensive understanding of the underlying physical principles and the corresponding theory remains elusive. The most common hypothesis is that functionalized nanoparticles transiently amplify magnetic fields, leading to improved cellular reprogramming efficiency.

Lasing Effect in Symmetrical van der Waals Heterostructured Metasurfaces Due to Lattice-Induced Multipole Coupling.

New practical ways to reach the lasing effect in symmetrical metasurfaces have been developed and theoretically demonstrated. Our approach is based on excitation of the resonance of an octupole quasi-trapped mode (OQTM) in heterostructured symmetrical metasurfaces composed of monolithic disk-shaped van der Waals meta-atoms featured by thin photoluminescent layers and placed on a substrate. We revealed that the coincidence of the photoluminescence spectrum maximum of these layers with the wavelength of high-quality OQTM resonance leads to the lasing effect.

Laser Synthesis of Cerium-Doped Garnet Nanoparticles.

The application of a pulsed laser ablation technique for the generation of cerium-doped garnet nanoparticles in liquids is investigated. The morphological and optical properties of the obtained nanoparticles are demonstrated. Features introduced by the single crystals of GdAlGaO:Ce, LuAlO:Ce, and YAlGaO:Ce from which the nanoparticles are generated, as well as the parameters of a liquid media on the garnet nanoparticle generation are experimentally studied using TEM and UV-Vis spectroscopy methods.

Trapped mode control in metasurfaces composed of particles with the form birefringence property.

Progress in developing advanced photonic devices relies on introducing new materials, discovered physical principles, and optimal designs when constructing their components. Optical systems operating on the principles of excitation of extremely high-quality factor trapped modes (also known as the bound states in the continuum, BICs) are of great interest since they allow the implementation of laser and sensor devices with outstanding characteristics. In this paper, we discuss how one can utilize the anisotropic properties of novel materials (transition metal dichalcogenides, TMDs), particularly, the bulk molybdenum disulfide (MoS), to realize the excitation of trapped modes in dielectric metasurfaces.

SERS uncovers the link between conformation of cytochrome c heme and mitochondrial membrane potential.

The balance between the mitochondrial respiratory chain activity and the cell's needs in ATP ensures optimal cellular function. Cytochrome c is an essential component of the electron transport chain (ETC), which regulates ETC activity, oxygen consumption, ATP synthesis and can initiate apoptosis. The impact of conformational changes in cytochrome c on its function is not understood for the lack of access to these changes in intact mitochondria.

Transition metal dichalcogenide nanospheres for high-refractive-index nanophotonics and biomedical theranostics.

Recent developments in the area of resonant dielectric nanostructures have created attractive opportunities for concentrating and manipulating light at the nanoscale and the establishment of the new exciting field of all-dielectric nanophotonics. Transition metal dichalcogenides (TMDCs) with nanopatterned surfaces are especially promising for these tasks. Still, the fabrication of these structures requires sophisticated lithographic processes, drastically complicating application prospects.

Anapole Meta-Atoms: Nonradiating Electric and Magnetic Sources.

The existence of classical nonradiating electromagnetic sources is one of the puzzling questions to date. Here, we investigate radiation properties of physical systems composed of a single ultrahigh permittivity dielectric hollow disk excited by electric or magnetic pointlike dipole antennas, placed inside the inner bore. Using analytical and numerical methods, we demonstrate that such systems can support anapole states with total suppression of far-field radiation and thereby exhibit the properties of electric or magnetic nonradiating sources.

Homogeneous enhancement of near-fields in all-dielectric metasurfaces with cluster-based unit cells.

To construct a dielectric analog of a spaser, we study several configurations of cluster-based unit cells for an all-dielectric metasurface characterized by resonant conditions of the trapped mode excitation. Excitation of the trapped mode is realized by performing either specific displacement of particles in the cluster or perturbation of the equidistantly spaced particles by off-centered holes. The latter approach is more advantageous for enhancement of the electric near-field with homogeneous distribution in-plane of the structure and strong field localization outside the high-refractive-index dielectric particles.

Experimental Demonstration of Surface Plasmon Polaritons Reflection and Transmission Effects.

Special integrated photonic surface structures composed of a dielectric semicircle ridge and a dielectric block placed on a metal substrate are proposed for the investigation of surface plasmon polariton (SPP) reflection and transmission effects. A fabrication method called microscope projection photolithography was employed for the preparation of the structures. Leakage radiation microscopy was applied for the excitation and observation of surface plasmon polaritons (SPPs).

Core-shell particles as efficient broadband absorbers in infrared optical range.

We demonstrate that efficient broadband absorption of infrared radiation can be obtained with deeply subwavelength spherical dielectric particles covered by a thin metal layer. Considerations based on Mie theory and the quasi-static approximation reveala wide range of configuration parameters, within which the absorption cross section reaches the geometrical one and exceeds more than by order of magnitude the scattering cross section in the infrared spectrum. We show that the absorption is not only efficient but also broadband with the spectral width being close to the resonant wavelength corresponding to the maximum of the absorption cross section.

Transverse Scattering and Generalized Kerker Effects in All-Dielectric Mie-Resonant Metaoptics.

All-dielectric resonant nanophotonics lies at the heart of modern optics and nanotechnology due to the unique possibilities to control scattering of light from high-index dielectric nanoparticles and metasurfaces. One of the important concepts of dielectric Mie-resonant nanophotonics is associated with the Kerker effect that drives the unidirectional scattering of light from nanoantennas and Huygens metasurfaces. Here we suggest and demonstrate experimentally a novel effect manifested in the nearly complete simultaneous suppression of both forward and backward scattered fields.

Broadband forward scattering from dielectric cubic nanoantenna in lossless media.

Dielectric photonics platform provides unique possibilities to control light scattering via utilizing high-index dielectric nanoantennas with peculiar optical signatures. Despite the intensively growing field of all-dielectric nanophotonics, it is still unclear how surrounding media affect scattering properties of a nanoantenna with complex multipole response. Here, we report on light scattering by a silicon cubic nanoparticle embedded in lossless media, supporting optical resonant response.

Enhanced absorption in all-dielectric metasurfaces due to magnetic dipole excitation.

All-dielectric nanophotonics lies at a forefront of nanoscience and technology as it allows to control light at the nanoscale using its electric and magnetic components. Bulk silicon does not experience any magnetic response, nevertheless, we demonstrate that the metasurface made of silicon parallelepipeds allows to excite the magnetic dipole moment leading to the broadening and enhancement of the absorption. Our investigations are underpinned by the numerical predictions and the experimental verifications.

Nano-Antennas Based on Silicon-Gold Nanostructures.

We experimentally realize nano-antennas based on hybrid silicon-gold nanoparticles (NPs). The silicon particles covered by clusters of small metal NPs are fabricated from a liquid phase under the effect of the laser irradiation. The complex nanoclusters containing both Si and Au components provide the enhancement of the near-field intensity and the resonant light scattering associated with excitation of multipole resonances in NPs.

Resonant suppression of light transmission in high-refractive-index nanoparticle metasurfaces.

High-refractive-index nanoparticle two-dimensional arrays have attracted a lot of interest recently, as they support both electric and magnetic resonances and can be implemented as functional metasurfaces. Here we show that under particular conditions, the all-dielectric nanoparticle metasurfaces can resonantly suppress transmission. As an important example, resonant electric and magnetic dipole (MD) responses of silicon nanoparticle arrays are considered in the air, as well as in the dielectric matrix in visible and infrared spectral ranges.

Direct Amplitude-Phase Near-Field Observation of Higher-Order Anapole States.

Anapole states associated with the resonant suppression of electric-dipole scattering exhibit minimized extinction and maximized storage of electromagnetic energy inside a particle. Using numerical simulations, optical extinction spectroscopy, and amplitude-phase near-field mapping of silicon dielectric disks, we demonstrate high-order anapole states in the near-infrared wavelength range (900-1700 nm). We develop the procedure for unambiguously identifying anapole states by monitoring the normal component of the electric near-field and experimentally detect the first two anapole states as verified by far-field extinction spectroscopy and confirmed with the numerical simulations.

The Synthesis of Hybrid Gold-Silicon Nano Particles in a Liquid.

We show that the laser ablation method can be efficiently employed for the synthesis of silicon nanoparticles (NP), which are characterized by a strong resonant optical response in the visible spectral range. A single layer composed of silicon NPs has been deposited from the colloidal solution generated by laser ablation. The formation of hybrid silicon-gold NPs as a result of the laser action on a mixed colloidal solution is observed.

Highly Stable Monocrystalline Silver Clusters for Plasmonic Applications.

Plasmonic sensor configurations utilizing localized plasmon resonances in silver nanostructures typically suffer from the rapid degradation of silver under ambient atmospheric conditions. In this work, we report on the fabrication and detailed characterization of ensembles of monocrystalline silver nanoparticles (NPs), which exhibit a long-term stability of optical properties under ambient conditions without any protective treatments. Ensembles with different densities (surface coverages) of size-selected NPs (mean diameters of 12.

Resonant forward scattering of light by high-refractive-index dielectric nanoparticles with toroidal dipole contribution.

In this Letter, we demonstrate and investigate the Kerker-type effect in high-index dielectric nanoparticles for which the third-order multipoles give a considerable contribution to the light scattering process. It is shown that the Kerker-type effect (strong suppression of the backward light scattering and, simultaneously, resonant forward light scattering) can be associated with the resonant excitation of a toroidal dipole moment in the system. This effect is realized due to the interference of the scattered waves generated by electric, magnetic, and toroidal dipole moments of high-index nanoparticles.

Probing cytochrome c in living mitochondria with surface-enhanced Raman spectroscopy.

Selective study of the electron transport chain components in living mitochondria is essential for fundamental biophysical research and for the development of new medical diagnostic methods. However, many important details of inter- and intramembrane mitochondrial processes have remained in shadow due to the lack of non-invasive techniques. Here we suggest a novel label-free approach based on the surface-enhanced Raman spectroscopy (SERS) to monitor the redox state and conformation of cytochrome c in the electron transport chain in living mitochondria.

Nonradiating anapole modes in dielectric nanoparticles.

Nonradiating current configurations attract attention of physicists for many years as possible models of stable atoms. One intriguing example of such a nonradiating source is known as 'anapole'. An anapole mode can be viewed as a composition of electric and toroidal dipole moments, resulting in destructive interference of the radiation fields due to similarity of their far-field scattering patterns.

The interplay between localized and propagating plasmonic excitations tracked in space and time.

In this work, the mutual coupling and coherent interaction of propagating and localized surface plasmons within a model-type plasmonic assembly is experimentally demonstrated, imaged, and analyzed. Using interferometric time-resolved photoemission electron microscopy the interplay between ultrashort surface plasmon polariton wave packets and plasmonic nanoantennas is monitored on subfemtosecond time scales. The data reveal real-time insights into dispersion and localization of electromagnetic fields as governed by the elementary modes determining the functionality of plasmonic operation units.

Laser printing of silicon nanoparticles with resonant optical electric and magnetic responses.

Silicon nanoparticles with sizes of a few hundred nanometres exhibit unique optical properties due to their strong electric and magnetic dipole responses in the visible range. Here we demonstrate a novel laser printing technique for the controlled fabrication and precise deposition of silicon nanoparticles. Using femtosecond laser pulses it is possible to vary the size of Si nanoparticles and their crystallographic phase.

Optical spectroscopy of single Si nanocylinders with magnetic and electric resonances.

Resonant electromagnetic properties of nanoparticles fabricated from high-index semiconductor or dielectric materials are very promising for the realization of novel nanoantennas and metamaterials. In this paper we study optical resonances of Si nanocylinders located on a silica substrate. Multipole analysis of the experimental scattering spectra, based on the decomposed discrete dipole approximation, confirms resonant excitation of electric and magnetic dipole modes in the Si nanocylinders.