Publications by authors named "Evgeny V Khramov"
Doping of nano- and microparticles of oxides with rare earth elements (REEs) is used to fine-tune their structural, optical, and electrochemical properties. On the way to establish the structure-property relationship, we dope tantalum oxide (TaO) particles with REEs to study their effect on the oxide structure and luminescence. TaO is highly perspective in medicine, catalysis, and optics, but its crystal structure is insufficiently studied.
View Article and Find Full Text PDFThe crystal and local structures of Czochralski-grown calcium orthovanadate (Ca(VO)) single crystals doped with over-stoichiometric 0.05 wt % MnO (CVO:0.05Mn) and annealed under different conditions are studied by single-crystal conventional and synchrotron X-ray diffraction, X-ray absorption spectroscopy, and electron paramagnetic resonance for the first time.
View Article and Find Full Text PDFLaser Ca(VO) single crystals (СVO; space group 3, = 21) with crystallochemical formula Ca1Ca2Ca3Ca4(Ca5 + Са5А)(V1V2V3)O grown by the Czochralski method were doped with МnO (CVO:МnO) and СoO (CVO:CoO) by high-temperature diffusion annealing. Statistical and local structures were comprehensively studied by single-crystal and powder synchrotron X-ray diffraction and conventional single-crystal X-ray diffraction as well as by X-ray absorption spectroscopy for the first time. The presence of Mn ions with a mixed formal charge and Co ions in the Ca2 (monocapped trigonal prism), Ca3 (two-capped trigonal prism), and Ca4 (octahedron) sites was revealed by diffraction methods.
View Article and Find Full Text PDFThe mechanism of Zr-BEA hydrothermal synthesis in fluoride media has been investigated through the detailed characterization of samples obtained at different synthesis times by XRD, XRF, TGA, multinuclear solid-state NMR, FTIR, SEM, TEM with EDS, XAS, and nitrogen sorption. The synthetic procedure involved hydrothermal crystallization of the gel with the following composition: 1SiO:0.54TEAOH:0.
View Article and Find Full Text PDFHeterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation.
Inorg Chem
September 2018
Article Synopsis
- The study explores the creation of new palladium-based complexes with indium(III) and gallium(III) acetates to develop heterometallic carboxylate complexes.
- Two specific Pd-In complexes were successfully synthesized and characterized using advanced techniques like X-ray crystallography.
- The Pd-In complex demonstrated catalytic activity in selective hydrogenation reactions, while the Pd-Ga complex proved to be unstable under certain conditions.