Static and Resonant Properties and Magnetic Phase Diagram of LiMnTeO.

Physical properties of the mixed-valent tellurate of lithium and manganese, LiMn2TeO6, were investigated in measurements of ac and dc magnetic susceptibility χ, magnetization M, specific heat Cp, electron spin resonance (ESR), and nuclear magnetic resonance (NMR) in the temperature range 2−300 K under magnetic field up to 9 T. The title compound orders magnetically in two steps at T1 = 20 K and T2 = 13 K. The intermediate phase at T2 < T < T1 is fully suppressed by magnetic field µ0H of about 4 T.

Effects of Non-Stoichiometry on the Ground State of the Frustrated System LiNiSbO.

The non-stoichiometric system LiNiSbO is a Li-deficient derivative of the zigzag honeycomb antiferromagnet LiNiSbO. Structural and magnetic properties of LiNiSbO were studied by means of X-ray diffraction, magnetic susceptibility, specific heat, and nuclear magnetic resonance measurements. Powder X-ray diffraction data shows the formation of a new phase, which is Sb-enriched and Li-deficient with respect to the structurally honeycomb-ordered LiNiSbO.

Tuning the spin coherence time of Cu(II)-(bis)oxamato and Cu(II)-(bis)oxamidato complexes by advanced ESR pulse protocols.

We have investigated with the pulsed ESR technique at X- and Q-band frequencies the coherence and relaxation of Cu spins = 1/2 in single crystals of diamagnetically diluted mononuclear [-BuN][Cu(opba)] (1%) in the host lattice of [-BuN][Ni(opba)] (99%, opba = -phenylenebis(oxamato)) and of diamagnetically diluted mononuclear [-BuN][Cu(opbo-Pr)] (1%) in the host lattice of [-BuN][Ni(opbo-Pr)] (99%, opbo-Pr = -phenylenebis((propyl)oxamidato)). For that we have measured the electron spin dephasing time at different temperatures with the two-pulse primary echo and with the special Carr-Purcell-Meiboom-Gill (CPMG) multiple microwave pulse sequence. Application of the CPMG protocol has led to a substantial increase of the spin coherence lifetime in both complexes as compared to the primary echo results.

Electron Spin Density on the N-Donor Atoms of Cu(II)-(Bis)oxamidato Complexes As Probed by a Pulse ELDOR Detected NMR.

We have applied the pulse ELDOR detected NMR (EDNMR) technique to determine the tensors of the transferred Cu (S = 1/2) - (14)N (I = 1) hyperfine (HF) interaction in single crystals of diamagnetically diluted mononuclear o-phenylenebis(N(R)-oxamide) complexes of [(n)Bu4N]2[Cu(opboR2)] (R = Et 1, (n)Pr 2) (1%) in a host lattice of [(n)Bu4N]2[Ni(opboR2)] (R = Et 3, (n)Pr 4) (99%) (1@3 and 2@4)). To facilitate the analysis of our EDNMR data and to analyze possible manifestations of the nuclear quadrupole interaction in the EDNMR spectra, we have treated a model electron-nuclear system of the coupled S = 1/2 and I = 1 spins using the spin density matrix formalism. It appears that this interaction yields a peculiar asymmetry of the EDMR spectra that manifests not only in the shift of the positions of the EDNMR lines that correspond to the forbidden EPR transitions, as expected, but also in the intensities of the EDNMR lines.

Magnetic superexchange interactions: trinuclear bis(oxamidato) versus bis(oxamato) type complexes.

The diethyl ester of o-phenylenebis(oxamic acid) (opbaH2Et2) was treated with an excess of RNH2 in MeOH to cause the exclusive formation of the respective o-phenylenebis(N(R)-oxamides) (opboH4R2, R = Me , Et , (n)Pr ) in good yields. Treatment of with half an equivalent of [Cu2(AcO)4(H2O)2] or one equivalent of [Ni(AcO)2(H2O)4] followed by the addition of four equivalents of [(n)Bu4N]OH resulted in the formation of mononuclear bis(oxamidato) type complexes [(n)Bu4N]2[M(opboR2)] (M = Ni, R = Me , Et , (n)Pr ; M = Cu, R = Me , Et , (n)Pr ). By addition of two equivalents of [Cu(pmdta)(NO3)2] to MeCN solutions of , novel trinuclear complexes [Cu3(opboR2)(L)2](NO3)2 (L = pmdta, R = Me , Et , (n)Pr ) could be obtained.