Supported ionic liquids as highly efficient and low-cost material for CO/CH separation process.

Physical immobilization of ionic liquids (ILs) in solid materials appears as an interesting strategy for the development of new sorbents for CO separation from natural gas. In this work the effect of physical immobilization of two ionic liquids with different anions (bmim[Cl] and bmim[OAc]) on two mesoporous supports (commercial silica SBA-15 and silica extracted from rice husk) was evaluated for CO separation from natural gas by experimental determination of CO sorption, CO/CH selectivity and sorption kinetics. Results showed that the pure supports present the greatest CO sorption capacity when compared to immobilized ILs.