All-Perovskite Multicomponent Nanocrystal Superlattices.

Nanocrystal superlattices (NC SLs) have long been sought as promising metamaterials, with nanoscale-engineered properties arising from collective and synergistic effects among the constituent building blocks. Lead halide perovskite (LHP) NCs come across as outstanding candidates for SL design, as they demonstrate collective light emission, known as superfluorescence, in single- and multicomponent SLs. Thus far, LHP NCs have only been assembled in single-component SLs or coassembled with dielectric NC building blocks acting solely as spacers between luminescent NCs.

Shape-Directed Co-Assembly of Lead Halide Perovskite Nanocubes with Dielectric Nanodisks into Binary Nanocrystal Superlattices.

Self-assembly of colloidal nanocrystals (NCs) holds great promise in the multiscale engineering of solid-state materials, whereby atomically engineered NC building blocks are arranged into long-range ordered structures-superlattices (SLs)-with synergistic physical and chemical properties. Thus far, the reports have by far focused on single-component and binary systems of spherical NCs, yielding SLs isostructural with the known atomic lattices. Far greater structural space, beyond the realm of known lattices, is anticipated from combining NCs of various shapes.

Reduction of Optical Gain Threshold in CsPbI Nanocrystals Achieved by Generation of Asymmetric Hot-Biexcitons.

Lead halide perovskite nanocrystals (NCs) are a class of promising light-emitting materials and have been considered as gain media in lasers. Strong exciton-exciton interactions in NCs cause an energy shift of the lowest optical transition and affect the optical gain threshold. Here, we clarify the dynamics of exciton-exciton interactions in highly photoexcited CsPbI NCs by double-pump transient absorption spectroscopy.