Publications by authors named "Ersin Guler"

Lead(ii) is an extremely toxic heavy metal ion that causes various health problems that are difficult to recover from in many developing countries of the world. Fluorescence-based nanosensors have amazing characteristics such as high sensitivity/selectivity, portability, low detection limit, rapid on-site usability, low cost and capability for removal of heavy metal ions. In this paper, a new fluorescent hybrid material based on silica gel (Bodipy-Si) was developed a click reaction between alkyne-terminal silica gel and azido-terminal Bodipy.

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A general synthetic method was improved to synthesize a chemosensor based on a tripodal Bodipy () structure. The product and its intermediate products were successfully prepared and fully characterized. The metal ion sensing performance of the tripodal compound was evaluated by UV/Vis and fluorescence spectroscopies.

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A fluorescent chemosensor including dual Bodipy units (d-BODIPY) was improved for selective copper (II) sensing in half-aqueous samples. The sensor d-BODIPY has a highly selective and sensitive detection towards Cu (II) over the studied competing for metal cations. The interaction among solutions of Cu (II) and d-BODIPY caused a crucial quenching effect in fluorescence maxima at 548 nm (λ = 470 nm) owing to the electronic trap occurring between the amide and triazole units.

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A new fluorescent chemosensor (Bodipy-S) derived from Bodipy and Salophen was developed. After the characterization of all compounds, the behavior of the chemosensor Bodipy-S toward p, d and f block-metal ions was investigated by UV-vis and fluorescence spectroscopy. This chemosensor can selectively detect to Cu (II) in methanol-aqueous solution based on chelation enhanced fluorescence (CHEF) and it almost exhibit to a fluorescence quenching effect with 20-fold.

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This manuscript describes a highly selective and ultra-sensitive detection of Ag(I) in aqueous solution using amine coated magnetite nanoparticles modified boron-dipyrromethene by spectrofluorometer. Fe3O4 nanoparticles were synthesized by co-precipitation of Fe(2+)and Fe(3+)in an ammonia solution. Amine modified Fe3O4 was prepared by using (3-aminopropyl)triethoxysilane as silanization agent.

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The aryl-amine containing azacrown ether ring and alkyl-chloro boradiazaindacene (Bodipy) were synthesized by Schiff base condensation. The absorption and emission of a novel Schiff base derivative (based on azacrown-Bodipy ) were performed in presence of different cations such as Zn, Ga, Pb, Hg, NH Ca, Cu, Na, Ni, Cd and Cr. The complexation property of the Schiff base was studied in dimethylformamide (DMF) by interacting azacrown-ether group and transition metal nitrates-ammonium chloride.

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A novel chemosensor based on calix[4]pyrrole derivative modified by Bodipy unit has been synthesized, and its complexes with various anions were investigated. The results show that the receptors can selectively recognize biologically important fluoride ions. The binding affinity for fluoride ions was investigated by naked-eye color change, absorption, emission, proton nuclear magnetic resonance spectroscopy.

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We presented the synthesis of a novel Schiff base and its complexation properties with some transition metal ions in this work. For this, the 2,3,4,6,7,10,11 hexahydroxytriphenylene (HHTP) as starting material was synthesized according to known procedure. Moreover, the 2-((2-chloroethylimino)methyl) phenol material was prepared with reaction of salicylaldehyde and 2-chloroethylamine hydrochloride.

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