Changes in organic matter composition caused by EDTA washing of two soils contaminated with toxic metals.

Two soils contaminated with potentially toxic metals (PTMs) contrasting in pH and mineralogy were remediated with CaEDTA, and changes in soil organic matter (SOM) composition were investigated. Previous studies showed no significant loss of SOM from CaEDTA-treated soils, but the results of our study reflected significant decreases (from 46 to 49%) in the free fraction of humic acids (HAs). Remediation affected the composition of the free HA fraction via disturbance of intermolecular bonds - an increase in phenolic and aromatic groups with a simultaneous decrease in carbohydrates - which was confirmed by FTIR spectroscopy in both soils.

The use of zero-valent Fe for curbing toxic emissions after EDTA-based washing of Pb, Zn and Cd contaminated calcareous and acidic soil.

The use of EDTA-based soil washing is prevented by chelant environmental persistence and the hazard of toxic post-remedial emissions. Calcareous and acidic soils with 828 and 673 mg Pb kg, respectively, and co-contaminated with Zn and Cd, were washed with 90 and 60 mM EDTA, respectively, to remove 67 and 80% of Pb. Washed soils were rinsed until 6.

EDTA retention and emissions from remediated soil.

EDTA-based remediation is reaching maturity but little information is available on the state of chelant in remediated soil. EDTA soil retention was examined after extracting 20 soil samples from Pb contaminated areas in Slovenia, Austria, Czech Republic and USA with 120 mM kg(-1) Na2H2EDTA, CaNa2EDTA and H4EDTA for 2 and 24 h. On average, 73% of Pb was removed from acidic and 71% from calcareous soils (24 h extractions).

Prediction of blood lead levels in children before and after remediation of soil samples in the upper Meza Valley, Slovenia.

The Meza Valley, Slovenia, has been contaminated by Pb smelting, resulting in an epidemic of lead poisoning in childhood. The potential of remediation with EDTA soil washing to mitigate the risk from Pb poisoning was investigated by applying the Integrated Exposure Uptake Bio-kinetic (IEUBK) model. Soils from 79 locations were collected and the total and bio-accessible Pb concentrations were determined before and after extraction with 60 mmol kg(-1) EDTA.