Impact of Concentration Polarization Phenomena on Gas Separation Processes with High-Performance Zeolite Membranes: Experiments vs. Simulations.

Polarization phenomena play a key role in membrane separation processes but remain largely unexplored for gas separations, where the mass transfer resistance is most often limited to the membrane. This assumption, which is commonly used today for the simulation of membrane gas separations, has to be reconsidered when high-performance materials, showing a very high permeance and/or selectivity, are used. In this study, a series of steady-state separation performances experimentally obtained on CO/CH mixtures with a zeolite membrane are compared to the predictions of a dedicated 1D approach, recently derived and validated through CFD simulations.

Design and Preparation a New Composite Hydrophilic/Hydrophobic Membrane for Desalination by Pervaporation.

Herein, experimental and theoretical approaches were used to design a new composite membrane for desalination by pervaporation. The theoretical approaches demonstrate the possibility to reach high mass transfer coefficients quite close to those obtained with conventional porous membranes if two conditions are verified: (i) a dense layer with a low thickness and (ii) a support with a high-water permeability. For this purpose, several membranes with a cellulose triacetate (CTA) polymer were prepared and compared with a hydrophobic membrane prepared in a previous study.

Experimental Proof of a Transformation Product Trap Effect with a Membrane Photocatalytic Process for VOC Removal.

The decomposition of volatile organic compounds by photocatalytic oxidation (PCO) has been widely studied. However, the technological development of this oxidative technique has to address how to handle the formation of transformation products. The work presented here investigates the original combination of a dense membrane separation process and PCO to intensify the trapping and reduction of PCO transformation products.

Membrane Separation Processes and Post-Combustion Carbon Capture: State of the Art and Prospects.

Membrane processes have been investigated for carbon capture for more than four decades. Important efforts have been more recently achieved for the development of advanced materials and, to a lesser extent, on process engineering studies. A state-of-the-art analysis is proposed with a critical comparison to gas absorption technology, which is still considered as the best available technology for this application.

Development of new pervaporation composite membranes for desalination: Membrane characterizations and experimental permeation data.

The data contained in this publication refers to a new approach to design composite pervaporation membranes that could be useful in water treatment. The work is based on the rational prediction of the membrane mass transfer coefficient using the resistance in series model and the corresponding experimental membranes were tested with several aqueous solutions comparatively to a commercially available porous distillation membrane (PVDF). All the related data, i.

Data supporting the validation of a simulation model for multi-component gas separation in polymeric membranes.

The article describes data concerning the separation performances of polymeric hollow-fiber membranes. The data were obtained using a model for simulating gas separation, described in the research article entitled "Interplay of inlet temperature and humidity on energy penalty for CO post-combustion capture: rigorous analysis and simulation of a single stage gas permeation process" (L. Giordano, D.

Comparison between numerical and experimental results on thermoconvective instabilities of a high-Prandtl-number liquid.

The flow structuration of silicon oil (Prandtl number of 10.3) in a open cylindrical pool heated from the center of the surface is investigated numerically. Our purpose is to perform the numerical simulation of experimental results obtained by Favre [Phys.