Publications by authors named "Eric C Sivret"

Passive liquid surfaces in wastewater treatment plants may be potential sources of odorous emissions. This study investigates the occurrence and significance of deviations that may originate from the use of the effective diameter as fetch parameter in the empirical correlations utilised by the WATER9 model to estimate odorous emissions at passive liquid surfaces. A sensitivity analysis was performed using benzene as a model compound and considering representative conditions of wind speed and wind alignment.

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Volatile sulfur and volatile organic compound (VSC and VOC, respectively) emissions were measured over a 3.5 year period from 21 field monitoring sites across Australia to determine their potential contribution to sewer odours and support the evaluation of odour abatement processes used to treat sewer emissions. Measured VOC concentrations were generally less than 250 μg/m(3), although some VOCs (toluene, trimethylbenzene and cymene) were present at higher concentrations.

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Article Synopsis
  • Odorous emissions from agriculture and waste management operations lead to community annoyance, primarily due to volatile sulfur compounds (VSCs) that are often lost during sampling.
  • The extent of VSC loss varies based on factors like storage time, bag materials, temperature, humidity, light, and the presence of other volatile organic compounds.
  • Experiments revealed that Tedlar bags retain 8-10% more hydrogen sulfide than Mylar and Nalophan bags; optimal conditions for maintaining at least 75% recovery of VSCs include ≤20°C, no light exposure, and a maximum storage time of 18 hours in Tedlar bags.
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Article Synopsis
  • The management of odorous emissions from sewer networks is crucial for operators, highlighting the need to understand the composition of volatile organic sulfur compounds (VOSCs).
  • A new method using thermal desorption and gas chromatography with a sulfur chemiluminescence detector has been developed to analyze a wider range of VOSCs, achieving optimized extraction conditions.
  • Seasonal, weekly, and diurnal studies in Sydney revealed consistent detection of several targeted compounds, with noticeable diurnal patterns indicating peak concentrations of hydrogen sulfide (H2S) and methanethiol (MeSH) occurring post-noon.
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Odorous emissions from sewers and wastewater treatment plants are a complex mixture of volatile chemicals that can cause annoyance to local populations, resulting in complaints to wastewater operators. Due to the variability in hedonic tone and chemical character of odorous emissions, no analytical technique can be applied universally for the assessment of odour abatement performance. Recent developments in analytical methodologies, specifically gas chromatography, odour assessment approaches (odour wheels, the odour profile method and dynamic olfactometry), and more recently combined gas chromatography-sensory analysis, have contributed to improvements in our ability to assesses odorous emissions in terms of odorant concentration and composition.

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An activated sludge aeration control concept was developed utilizing off-gas nitrous oxide concentrations as a surrogate for autotrophic nitrifying bacterial inhibition and aeration air as a master control variable. The control concept was evaluated using a simulated pilot scale bioreactor (mathematically calibrated liquid phase process model and a model to link off-gas nitrous oxide generation to liquid phase conditions) as a data generator. When applied to the simulated system, the process controller was successful at maintaining the process at the desired operating setpoint and promoting stable operation by minimizing periods of significant inhibition.

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