J Colloid Interface Sci
March 2025
It is of great significance but remains challenging to simultaneously development cost-effective and efficient non-noble metal electrocatalysts (NNMEs) for oxygen reduction reaction (ORR) in both alkaline and acidic solutions. In current work, a multi-component synergism system is developed, which is comprised of molybdenum phosphide (MoP) shell onto iron phosphide clusters anchored on carbon matrixes that embedded with numerous FeN species (MoP/FeP-FeN). The optimized MoP/FeP-FeN electrocatalyst delivers a synergistic enhancement in both alkaline and acidic ORR performances: E: 0.
View Article and Find Full Text PDFHydrogen production from seawater remains challenging due to the deactivation of the hydrogen evolution reaction (HER) electrode under high current density. To overcome the activity-stability trade-offs in transition-metal sulfides, we propose a strategy to engineer sulfur migration by constructing a nickel-cobalt sulfides heterostructure with nitrogen-doped carbon shell encapsulation (CN@NiCoS) electrocatalyst. State-of-the-art ex situ/in situ characterizations and density functional theory calculations reveal the restructuring of the CN@NiCoS interface, clearly identifying dynamic sulfur migration.
View Article and Find Full Text PDFIn seawater, severe hydroxide-based precipitation on the hydrogen evolution reaction (HER) electrode surface is still a major stumbling block for direct seawater electrolysis. Here, we design a direct seawater HER electrode with excellent anti-precipitation performance based on an Ni(OH) nanofiltration membrane grown on nickel foam (NF) at room temperature. The positively charged Ni(OH) membrane with nanometer-scale cracks realises an ion sieving function, which apparently hinders the transfer of Mg/Ca ions to suppress precipitation, while rapidly transporting OH and HO to ensure HER mass transfer.
View Article and Find Full Text PDFBackground: The use of antidepressant therapy alone has a limited efficacy in patients with childhood trauma-associated major depressive disorder (MDD). However, the effectiveness of antidepressant treatment combined with psychodrama in these patients is unclear.
Aim: To evaluate the effectiveness of antidepressant treatment combined with psychodrama.
Integrating femtosecond lasers with electron microscopies has enabled direct imaging of transient structures and morphologies of materials in real time and space. Here, we report the development of a laser-free ultrafast electron microscopy (UEM) offering the same capability but without requiring femtosecond lasers and intricate instrumental modifications. We create picosecond electron pulses for probing dynamic events by chopping a continuous beam with a radio frequency (RF)-driven pulser with the pulse repetition rate tunable from 100 MHz to 12 GHz.
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2020
Rational electrode design is crucial to promote the performance of the hydrogen evolution reaction (HER) via further enhancing the activity, stability, and utilization of platinum (Pt) in an alkaline electrolyte. Herein, a binder-free low-Pt-content HER electrode, Pt (∼20 μg cm) decorated on nickel hydroxide grown on nickel foam (Pt-Ni(OH)-2h-NF20), is fabricated at near room temperature in a test tube. To lower the ohmic resistance, for the first time, the Pt nanoparticles were location-selectively anchored on the bottom of height-controlled vertical Ni(OH) nanosheets via utilizing the mass transfer resistance of the dense Ni(OH) film for chloroplatinate.
View Article and Find Full Text PDFThe diamond amplifier (DA) is a new device for generating high-current, high-brightness electron beams. Our transmission-mode tests show that, with single-crystal, high-purity diamonds, the peak current density is greater than 400 mA/mm², while its average density can be more than 100 mA/mm². The gain of the primary electrons easily exceeds 200, and is independent of their density within the practical range of DA applications.
View Article and Find Full Text PDFZhonghua Fu Chan Ke Za Zhi
April 2005
Objective: To evaluate the effect of preoperative chemotherapy on bulky cervical cancer by internal iliac arterial infusion.
Methods: One hundred and eighty-six patients with bulky cervical cancer were randomly divided into two groups: chemotherapy + radiotherapy group (C + R group, n = 105) and radiotherapy group (R group, n = 81). Patients in C + R group underwent internal iliac arterial infusion chemotherapy by using Seldinger technique internal iliac arterial or epigastric arterial catheterization.