Metal halide perovskites are mixed ionic-electronic semiconductors that involve an important and particular phenomenology that negatively affects the performance and stability of next-generation photovoltaic devices based on such material. The ionic nature of perovskites is shown to undergo not only a simple redistribution of charges but also influences the electronic processes and ultimately the steady-state device operation. Nevertheless, a comprehensive understanding of the internal contributions of ionic and electronic conductivities to the evolution of current during device performance experiments and to degradation losses in ageing tests is currently missing.
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