Melting Kinetics of Nascent Poly(tetrafluoroethylene) Powder.

The melting behavior of nascent poly(tetrafluoroethylene) (PTFE) was investigated by way of differential scanning calorimetry (DSC). It is well known that the melting temperature of nascent PTFE is about 344 ∘ C, but reduces to 327 ∘ C for once molten material. In this study, the melting temperature of nascent PTFE crystals was found to strongly depend on heating rate, decreasing considerably for slow heating rates.

Effect of Self-Assembly of Oxalamide Based Organic Compounds on Melt Behavior, Nucleation, and Crystallization of Isotactic Polypropylene.

We report on the effect of an aliphatic oxalamide based nucleating agent () on the melt and crystallization behavior of isotactic polypropylene (PP) under defined shear conditions. Through polarized optical microscopy, we demonstrate that self-assembles from the PP melt into rhombic crystals whereas their size and distribution proved highly dependent on the employed cooling rates. The presence of 0.

Deformation-Induced Phase Transitions in iPP Polymorphs.

This detailed study reveals the relation between structural evolution and the mechanical response of α -, β - and γ -iPP. Uni-axial compression experiments, combined with in situ WAXD measurements, allowed for the identification of the evolution phenomena in terms of phase composition. Tensile experiments in combination with SAXS revealed orientation and voiding phenomena, as well as structural evolution in the thickness of the lamellae and amorphous layers.