Chemical composition and trophic state of shallow saline steppe lakes in central Asia (North Kazakhstan).

The purpose of this study was to identify the prevailing chemical composition and trophic state of the shallow saline steppe lakes of North Kazakhstan along a wide size range (< 1-454 km) and salinity gradient (2-322 g L) on a large spatial scale (1000 km), taking into account the potential effects of human disturbances. Water depth, Secchi disk transparency, temperature, pH, electric conductivity, major ions, total dissolved solids, total organic carbon, total nitrogen and phosphorus, nitrate, soluble reactive phosphorus, and chlorophyll a were measured. The equivalent percentage of major ions, Spearman rank correlation, multivariate analyses, equilibrium state of lakes, and spatial GIS autocorrelation were calculated.

Relationship between arsenic content of food and water applied for food processing.

As part of a survey conducted by the Central Agricultural Office of Hungary, 67 food samples including beverages were taken from 57 food industrial and catering companies, 75% of them being small and medium-sized enterprises (SMEs). Moreover, 40% of the SMEs were micro entities. Water used for food processing was simultaneously sampled.

Study on the leaching of phthalates from polyethylene terephthalate bottles into mineral water.

Carbonated and non-carbonated mineral water samples bottled in 0.5-L, 1.5-L and 2.

Impact of two iron(III) chelators on the iron, cadmium, lead and nickel accumulation in poplar grown under heavy metal stress in hydroponics.

Poplar (Populus jacquemontiana var. glauca cv. Kopeczkii) was grown in hydroponics containing 10 μM Cd(II), Ni(II) or Pb(II), and Fe as Fe(III) EDTA or Fe(III) citrate in identical concentrations.

Accumulation and distribution of iron, cadmium, lead and nickel in cucumber plants grown in hydroponics containing two different chelated iron supplies.

Cucumber plants grown in hydroponics containing 10 μM Cd(II), Ni(II) and Pb(II), and iron supplied as Fe(III) EDTA or Fe(III) citrate in identical concentrations, were investigated by total-reflection X-ray fluorescence spectrometry with special emphasis on the determination of iron accumulation and distribution within the different plant compartments (root, stem, cotyledon and leaves). The extent of Cd, Ni and Pb accumulation and distribution were also determined. Generally, iron and heavy-metal contaminant accumulation was higher when Fe(III) citrate was used.

Leaching of antimony from polyethylene terephthalate (PET) bottles into mineral water.

The Sb leaching from polyethylene terephthalate (PET) package material into 10 different brands of still (non-carbonated) and sparkling (carbonated) Hungarian mineral water purchased in supermarkets was investigated by inductively coupled plasma sector field mass spectrometry (ICP-SF-MS). The Sb concentration measured in PET package materials varied between 210 and 290 mg/kg. Generally, the Sb concentration of still mineral water was lower than that of sparkling in the case of identical storage time.

Influence of different bentonites on the rare earth element concentrations of clarified Romanian wines.

The rare earth element (REE) concentrations of 19 Romanian young wine samples originating from the Dealurile Moldovei viticulture area were determined by double focusing inductively coupled plasma mass spectrometry (DF-ICP-MS) after microwave-assisted digestion with nitric acid. The determination of Eu was hampered by the BaO molecular interference. Generally, the red wine samples were more concentrated for REEs than the white wine samples studied.

Investigation of iron pools in cucumber roots by Mössbauer spectroscopy: direct evidence for the Strategy I iron uptake mechanism.

Distinct chemical species of iron were investigated by Mössbauer spectroscopy during iron uptake into cucumber roots grown in unbuffered nutrient solution with or without 57Fe-citrate. Mössbauer spectra of iron deficient roots supplied with 10-500 microM 57Fe-citrate for 30-180 min and 24 h and iron-sufficient ones, were recorded. The roots were analysed for Fe concentration and Fe reductase activity.

Nafion/2,2'-bipyridyl-modified bismuth film electrode for anodic stripping voltammetry.

This paper describes the fabrication, characterisation and the application of a Nafion/2,2'-bipyridyl/bismuth composite film-coated glassy carbon electrode (NC(Bpy)BiFE) for the anodic stripping voltammetric determination of trace metal ions (Zn2+, Cd2+ and Pb2+). The NC(Bpy)BiFE electrode is prepared by first applying a 2.5 mm3 drop of a coating solution containing 0.

Arsenic speciation in xylem sap of cucumber (Cucumis sativus L.).

Flow injection analysis (FIA) and high-performance liquid chromatography double-focusing sector field inductively coupled plasma mass spectrometry (HPLC-DF-ICP-MS) were used for total arsenic determination and arsenic speciation of xylem sap of cucumber plants (Cucumis sativus L.) grown in hydroponics containing 2 micromol dm(-3) arsenate or arsenite, respectively. Arsenite [As(III)], arsenate [As(V)] and dimethylarsinic acid (DMA) were identified in the sap of the plants.