Theoretical and experimental studies have shown that activity concentrations of fallout radionuclides (such as Cs and excess Pb) decrease with particles size in aqueous suspensions. This paper is aimed at reviewing the theoretical fundamentals for granulometric speciation of radionuclides, and at exploring its practical use in the analytical context of gamma spectrometry for the radiometric dating of recent sediments, with view to: i) improving the detection of Cs (since its use as independent chronostratigraphic mark is challenging in the southern hemisphere because its low fallout rate), ii) supporting refined CIC models and normalization techniques in Pb-based radiogeochronologies. The work uses surface sediments sampled from the Tinto Estuary (SW Spain), affected by mining and phosphate-fertilizer industries, and from the Ankobra Estuary (Ghana), affected by intensive artisanal gold-mining.
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