Nanoscale polymer discs, toroids and platelets: a survey of their syntheses and potential applications.

Polymer self-assembly has become a reliable and versatile workhorse to produce polymeric nanomaterials. With appropriate polymer design and monomer selection, polymers can assemble into shapes and morphologies beyond well-studied spherical and cylindrical micellar structures. Steadfast access to anisotropic polymer nanoparticles has meant that the fabrication and application of 2D soft matter has received increasing attention in recent years.

Tunable Polymer Nanoreactors from RAFT Polymerization-Induced Self-Assembly: Fabrication of Nanostructured Carbon-Coated Anatase as Battery Anode Materials with Variable Morphology and Porosity.

We demonstrate a modular synthesis approach to yield mesoporous carbon-coated anatase (denoted as TiO/C) nanostructures. Combining polymerization-induced self-assembly (PISA) and reversible addition-fragmentation chain-transfer (RAFT) dispersion polymerization enabled the fabrication of uniform core-shell polymeric nanoreactors with tunable morphologies. The nanoreactors comprised of a poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) shell and a poly(benzyl methacrylate) (PBzMA) core.

Versatile Synthesis of Amino Acid Functional Polymers without Protection Group Chemistry.

The copolymerization of N-isopropylacrylamide (NiPAm) with aldehyde functional monomers facilitates postpolymerization functionalization with amino acids via reductive amination, negating the need for protecting groups. In reductive amination, the imine formed from the condensation reaction between an amine and an aldehyde is reduced to an amine. In this work, we categorize amino acids into four classes based on the functionality of their side chains (acidic, polar neutral, neutral, and basic) and use their amine groups in condensation reactions with aldehyde functional polymers.