Electrochemical Deposition of Silver Nanoparticle Assemblies on Carbon Ultramicroelectrode Arrays.

Silver nanoparticle (AgNP) assemblies combined with electrode surfaces have a myriad of applications in electrochemical energy storage and conversion devices, (bio)sensor development, and electrocatalysis. Among various nanoparticle synthesis methods, electrochemical deposition is advantageous due to its ability to control experimental parameters, enabling the formation of low-nanoscale (<50 nm) particles with narrow size distributions. Herein, we report the electrodeposition of AgNPs on a unique electrode platform based on carbon ultramicroelectrode arrays (CUAs), exploring several experimental variables including potential, time, and silver ion concentration.