The cadmium copper hydroxide nitrate, CdCu(3)(OH)(6)(NO(3))(2).0.5H(2)O, is furnished from oxygenated suspensions of Cu(2)O in aqueous Cd(NO(3))(2).
View Article and Find Full Text PDFThe syntheses and magnetic susceptibilities of a pure series of rare copper minerals from the atacamite family with general formula ZnxCu4-x(OH)6Cl2 (0 = x = 1) are reported. The structure of these compounds features a corner-sharing triangular kagomé lattice of antiferromagnetically coupled Cu(II) ions. We correlate the onset of magnetic ordering with the mole fraction of paramagnetic Cu(II) ions located between kagomé layers and demonstrate that the fully Zn-substituted compound shows no magnetic ordering down to 2 K, resulting in a highly spin-frustrated S = 1/2 lattice.
View Article and Find Full Text PDFThe tumor suppressor protein BRCA1 has been shown to enhance p53 transcription, whereas activated p53 represses BRCA1 transcription. To further understand the functional interaction of these proteins, we investigated the role of BRCA1 in p53-induced phenotypes. We found that BRCA1 when subjected to forced expression acts synergistically with wild-type p53, resulting in irreversible growth arrest, as shown by VhD mouse fibroblast cells expressing a temperature-sensitive mutant of p53.
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